65672

(S)-1-{(S_P)-2-[2-(二苯基膦)苯基]二茂铁基}乙基双[3,5-双-(三氟甲基)苯基]膦

≥97%

• 同義詞: (1R)-1-[(1S)-1-[双(3,5-双(三氟甲基)苯基)膦]乙基]-2-[2-(二苯基膦)苯基]二茂铁（符合 CAS 标准）, Walphos SL-W001-2
• 經驗公式（希爾表示法）: C₄₆H₃₂F₁₂FeP₂
• CAS號碼: 849925-17-3
• 分子量：: 930.52
• MDL號碼: MFCD04117710
• 分類程式碼代碼: 12352101
• PubChem物質ID: 24884221
• NACRES: NA.22

屬性

• 品質等級: 100
• 化驗: ≥97%
• 光學純度: ee: ≥99%
• 官能基: fluoro; phosphine
• SMILES 字串: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
• InChI: 1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m1../s1
• InChI 密鑰: LKNKYBWIZNAXBY-KHZPMNTOSA-N

描述

一般說明

与 Solvias AG 合作销售

應用

(S)-1-{(SP)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine can be used:

• To prepare sulfide-capped triruthenium hydrido clusters containing Walphos ligands, which are employed as catalysts for asymmetric hydrogenation of tiglic acid (trans-2-methyl-2-butenoic acid).
• As a ligand in the reductive allylic alkylation of unsaturated carbonyl compounds using Pd catalyst.

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)