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About This Item
線性公式:
LiAlH4
CAS號碼:
分子量::
37.95
EC號碼:
MDL號碼:
分類程式碼代碼:
26111700
PubChem物質ID:
NACRES:
NA.22
推薦產品
化驗
≥97.0% (gas-volumetric)
形狀
tablet (5 g each)
反應適用性
reagent type: reductant
mp
125 °C (dec.) (lit.)
SMILES 字串
[Li].[AlH3]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI 密鑰
OCZDCIYGECBNKL-UHFFFAOYSA-N
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其他說明
综述
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1A - Water-react 1
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類(WGK)
WGK 1
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
H.C. Brown et al.
Tetrahedron, 35, 567-567 (1979)
Diastereoselective reductive amination of aryl trifluoromethyl ketones and alpha-amino esters.
Greg Hughes et al.
Angewandte Chemie (International ed. in English), 46(11), 1839-1842 (2007-04-24)
Krishnananda Samanta et al.
Bioorganic & medicinal chemistry letters, 20(1), 283-287 (2009-11-26)
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reduction, followed by debenzylation and finally intramolecular Mitsunobu cyclization. The new benzoxazepines specifically inhibited growth
Damián E Bikiel et al.
Inorganic chemistry, 44(15), 5286-5292 (2005-07-19)
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4). We have employed a combination of theoretical and experimental
Vito Capriati et al.
Organic letters, 4(14), 2445-2448 (2002-07-06)
[reaction: see text] The stereospecific alpha-lithiation of optically active styrene oxides and the trapping reaction of the corresponding highly reactive intermediates with electrophiles to produce optically active styrene oxide derivatives are described. This methodology has been applied to the synthesis
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