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Key Documents

529745

Sigma-Aldrich

异丙基锂 溶液

0.7 M in pentane

同義詞:

2-Lithiopropane, 2-Propyllithium

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About This Item

線性公式:
(CH3)2CHLi
CAS號碼:
分子量::
50.03
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

品質等級

濃度

0.7 M in pentane

bp

35-36 °C

密度

0.632 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

[Li]C(C)C

InChI

1S/C3H7.Li/c1-3-2;/h3H,1-2H3;

InChI 密鑰

HDSLTIHESBGENB-UHFFFAOYSA-N

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應用

用于研究 N-磺酰基保护氮杂环丙烷的烷基开环反应,生成氨基醇和醚。

包裝

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Central nervous system

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 3

閃點(°F)

-31.0 °F - closed cup

閃點(°C)

-35 °C - closed cup


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David M Hodgson et al.
The Journal of organic chemistry, 71(22), 8510-8515 (2006-10-27)
Organolithium-induced alkylative ring opening of N-sulfonyl-protected aziridinyl ethers is described. The reactions were efficiently carried out with a variety of organolithiums, providing a promising new strategy to unsaturated amino alcohols and ethers. Cis- and trans-1,4-dimethoxybut-2-ene-derived aziridines were prepared, and their

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