推薦產品
品質等級
化驗
≥99.0%
折射率
n20/D 1.415
bp
65-66 °C (lit.)
密度
0.707 g/mL at 20 °C (lit.)
官能基
allyl
SMILES 字串
C\C=C/CC=C
InChI
1S/C6H10/c1-3-5-6-4-2/h3-4,6H,1,5H2,2H3/b6-4-
InChI 密鑰
PRBHEGAFLDMLAL-XQRVVYSFSA-N
一般說明
cis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)5 affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated.
訊號詞
Danger
危險聲明
防範說明
危險分類
Acute Tox. 3 Oral - Asp. Tox. 1 - Flam. Liq. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
-50.8 °F - closed cup
閃點(°C)
-46 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Reaction of cis-1, 4-Hexadiene with Iron Pentacarbonyl.
Bulletin of the Chemical Society of Japan, 41(6), 1483-1484 (1968)
Nickel-promoted methylvinylcyclopropane rearrangements. Mechanistic relevance to the cis-1, 4-hexadiene to 2-methyl-1, 3-pentadiene isomerization.
Journal of the American Chemical Society, 96(13), 4229-4234 (1974)
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