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重要文件

49800

Sigma-Aldrich

D -(+)-甘油醛

≥98.0% (HPLC)

同義詞:

(2R)-2,3-Dihydroxypropanal, Triose

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About This Item

經驗公式(希爾表示法):
C3H6O3
CAS號碼:
分子量::
90.08
Beilstein:
1720474
EC號碼:
MDL號碼:
分類程式碼代碼:
12352200
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥98.0% (HPLC)

雜質

≤10% water

儲存溫度

2-8°C

SMILES 字串

OC[C@@H](O)C=O

InChI

1S/C3H6O3/c4-1-3(6)2-5/h1,3,5-6H,2H2/t3-/m0/s1

InChI 密鑰

MNQZXJOMYWMBOU-VKHMYHEASA-N

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相關類別

應用

D-(+)-甘油醛可用作合成以下物质的反应物:
  • (S)-高苯丙氨酸,通过胺和α-羟醛偶联生成的3-氨基-1,2-二醇的钌氧化制备。
  • β- 和γ-联烯醇,通过金属催化环化制备。联烯醇是制备对映体纯的二氢吡喃和四氢噁英(tetrahydrooxepine)的关键前体。
  • 异亚丙基D-甘油醛中间体,其控制前列腺素(PGE1)的总合成中的手性。

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves


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分析證明 (COA)

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Highly stereocontrolled one-step synthesis of anti-β-amino alcohols from organoboronic acids, amines, and α-hydroxy aldehydes
Petasis NA and Zavialov IA
Journal of the American Chemical Society, 120(45), 11798-11799 (1998)
Chiral synthesis of prostaglandins (PGE1) from D-glyceraldehyde
Stork G and Takahashi T
Journal of the American Chemical Society, 99(4), 1275-1276 (1977)
Takayoshi Wakagi et al.
PloS one, 11(1), e0147333-e0147333 (2016-01-26)
Archaea use glycolytic pathways distinct from those found in bacteria and eukaryotes, where unique enzymes catalyze each reaction step. In this study, we isolated three isozymes of glyceraldehyde oxidoreductase (GAOR1, GAOR2 and GAOR3) from the thermoacidophilic archaeon Sulfolobus tokodaii. GAOR1-3
Katarzyna Lechowicz et al.
International journal of molecular sciences, 21(16) (2020-08-13)
Lolium multiflorum/Festuca arundinacea introgression forms have been proved several times to be good models to identify key components of grass metabolism involved in the mechanisms of tolerance to water deficit. Here, for the first time, a relationship between photosynthetic and
Metal-Catalyzed Cyclization of β-and γ-Allenols Derived from d-Glyceraldehyde- Synthesis of Enantiopure Dihydropyrans and Tetrahydrooxepines: An Experimental and Theoretical Study
Alcaide BL
Chemistry?A European Journal, 15(36), 9127-9138 (2009)

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