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Key Documents

481521

Sigma-Aldrich

三氯化六氨合钴

99%

同義詞:

氯化六氨合钴, 氯化钴六胺络合物

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About This Item

線性公式:
[Co(NH3)6]Cl3
CAS號碼:
分子量::
267.48
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

化驗

99%

形狀

powder

mp

217 °C (lit.)

溶解度

H2O: slightly soluble(lit.)
ethanol: insoluble(lit.)

密度

1.71 g/mL at 25 °C (lit.)

SMILES 字串

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Co+3]

InChI

1S/3ClH.Co.6H3N/h3*1H;;6*1H3/q;;;+3;;;;;;/p-3

InChI 密鑰

JXBGZYGSWFSYFI-UHFFFAOYSA-K

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一般說明

氯化六胺钴(III)可作为原料合成制备各种Co基纳米材料,如Co-Sb纳米合金,Co纳米胶囊,双金属纳米颗粒,和共聚物纳米复合材料。这些材料被用于催化,电解质和再生能源转换装置领域。

應用

  • 铼(VII)化合物作为合成有机反应催化剂的无机前体:研究了六胺钴(III)氯化物作为催化有机反应的商业产品替代品的潜力,强调了其在合成化学中的作用(K Leszczyńska-Sejda et al., 2019)。
  • 原位形成用于可见光水氧化的分子钴(iii)/AgCl光催化剂:讨论了六胺钴(III)氯的合成和应用,形成一种新型光催化剂用于水氧化,这是太阳能利用的关键过程(H Mogi et al., 2021)。

象形圖

Health hazard

訊號詞

Danger

危險分類

Aquatic Chronic 4 - Carc. 2 - Resp. Sens. 1 - Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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P M Littlewood et al.
Brain research, 445(1), 165-170 (1988-03-29)
Intracellular injection of hexamminecobaltic chloride into a neurone causes characteristic changes to the structure of its mitochondria. This provides a simple technique to label neuronal profiles for examination of their ultrastructure. Synaptic structures are not affected by hexamminecobaltic ions.
Pinpinat Malaikaew et al.
Journal of photochemistry and photobiology. B, Biology, 103(3), 251-255 (2011-05-03)
In this study, a new small-molecule-based reagent was designed to recognize and bind to specific site in protein. A new pyrenyl probe, d-biotinyl-1(1-pyrene)methylamide (Py-biotin) was designed and synthesized by coupling of d-biotin to 1(1-pyrene)methylamine hydrochloride. Binding studies and site-specific photocleavage
Michael G Poirier et al.
Journal of cellular biochemistry, 85(2), 422-434 (2002-04-12)
We show that the chromatin in mitotic chromosomes can be drastically overcompacted or unfolded by temporary shifts in ion concentrations. By locally 'microspraying' reactants from micron-size pipettes, while simultaneously monitoring the size of and tension in single chromosomes, we are
T Allers et al.
Nucleic acids research, 28(2), e6-e6 (1999-12-22)
The Holliday junction is a central intermediate in genetic recombination. This four-stranded DNA structure is capable of spontaneous branch migration, and is lost during standard DNA extraction protocols. In order to isolate and characterize recombination intermediates that contain Holliday junctions
D C Tessier et al.
Analytical biochemistry, 158(1), 171-178 (1986-10-01)
Despite its unique ability to ligate single-stranded DNA molecules, T4 RNA ligase has so far seen little use in molecular biology due to long reaction times, modest yields, and apparent inability to promote ligation of long oligodeoxyribonucleotides. We describe here

文章

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

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