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Merck
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重要文件

459798

Sigma-Aldrich

烯丙醇

≥98.5%

同義詞:

2-丙烯-1-醇

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About This Item

線性公式:
CH2=CHCH2OH
CAS號碼:
分子量::
58.08
Beilstein:
605307
EC號碼:
MDL號碼:
分類程式碼代碼:
12352200
PubChem物質ID:
NACRES:
NA.21

蒸汽密度

2 (vs air)

品質等級

蒸汽壓力

23.8 mmHg ( 25 °C)

化驗

≥98.5%

自燃溫度

712 °F

expl. lim.

18 %

折射率

n20/D 1.412 (lit.)

bp

96-98 °C (lit.)

mp

−129 °C (lit.)

密度

0.854 g/mL at 25 °C (lit.)

官能基

hydroxyl

SMILES 字串

OCC=C

InChI

1S/C3H6O/c1-2-3-4/h2,4H,1,3H2

InChI 密鑰

XXROGKLTLUQVRX-UHFFFAOYSA-N

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應用

用于诱导肝脏损坏的小鼠模型,该模型用于研究肝细胞毒性和肝干细胞介导修复的机制。

訊號詞

Danger

危險分類

Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

71.6 °F - closed cup

閃點(°C)

22 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Hydrosilylation of allyl alcohol with [HSiMe2OSiO1.5]8: octa (3-hydroxypropyldimethylsiloxy) octasilsesquioxane and its octamethacrylate derivative as potential precursors to hybrid nanocomposites.
Zhang C and Laine RM.
Journal of the American Chemical Society, 122(29), 6979-6988 (2000)
Gregory M Mullen et al.
Journal of the American Chemical Society, 136(17), 6489-6498 (2014-04-08)
Partial oxidation of alcohols is a topic of great interest in the field of gold catalysis. In this work, we provide evidence that the partial oxidation of allyl alcohol to its corresponding aldehyde, acrolein, over oxygen-precovered gold surfaces occurs via
Deoxydehydration of glycerol to allyl alcohol catalyzed by rhenium derivatives.
Canale V, et al.
Catalysis Science & Technology, 4(10), 3697-3704 (2014)
James Y Hamilton et al.
Journal of the American Chemical Society, 135(3), 994-997 (2012-12-22)
The first example of Ir-catalyzed asymmetric substitution reaction with vinyl trifluoroborates is described. The direct reaction between branched, racemic allylic alcohols and potassium alkenyltrifluoroborates proceeded with high site selectivity and excellent enantioselectivity (up to 99%) mediated by an Ir-(P,olefin) complex.
Johanna M Larsson et al.
Journal of the American Chemical Society, 135(1), 443-455 (2012-12-04)
The mechanism of the palladium-catalyzed synthesis of allylic silanes and boronates from allylic alcohols was investigated. (1)H, (29)Si, (19)F, and (11)B NMR spectroscopy was used to reveal key intermediates and byproducts of the silylation reaction. The tetrafluoroborate counterion of the

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