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重要文件

455571

Sigma-Aldrich

硼氢化钾

≥97%

同義詞:

硼氢化钾

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About This Item

線性公式:
KBH4
CAS號碼:
分子量::
53.94
EC號碼:
MDL號碼:
分類程式碼代碼:
12352306
PubChem物質ID:
NACRES:
NA.22

等級

for analytical purposes

品質等級

化驗

≥97%

形狀

powder

反應適用性

reagent type: reductant

mp

500 °C (dec.) (lit.)

密度

1.18 g/mL at 25 °C (lit.)

SMILES 字串

[K+].[H][B-]([H])([H])[H]

InChI

1S/BH4.K/h1H4;/q-1;+1

InChI 密鑰

ICRGAIPBTSPUEX-UHFFFAOYSA-N

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應用

硼氢化钾(KBH4)可用作合成以下物质的还原剂:       
  • 通过还原铜盐制备铜纳米粒子。
  • 在手性NN′-二氧基钪(III)复合物催化剂存在下,通过烯酮和酮还原制备对映选择性烯丙醇。
  • 在相转移催化剂PEG-400的存在下,通过还原硝基芳烃来制备乙氧基苯。

它也可以用作镍-硼合金中的硼源,该合金可电沉积在碳纤维上以改善碳的催化石墨化作用。

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

nwg

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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S. Yan and S. Zhang,
International Journal of Hydrogen Energy, 36, 13392-13397 (2011)
A. Yin, et al.,
Applied Catalysis, 400, 39-47 (2011)
Gang Lian et al.
Dalton transactions (Cambridge, England : 2003), 40(26), 6961-6967 (2011-06-07)
Cubic boron nitride (cBN) is synthesized by a low-temperature solid state synthesis and in situ phase transformation route with NH(4)BF(4), B, NaBH(4) and KBH(4) as the boron sources and NaN(3) as the nitrogen source. Furthermore, two new strategies are developed
Feng Li et al.
Journal of chromatography. A, 1081(2), 232-237 (2005-07-26)
A novel method for speciation analysis of inorganic arsenic was developed by on-line hyphenating microchip capillary electrophoresis (chip-CE) with hydride generation atomic fluorescence spectrometry (HG-AFS). Baseline separation of As(III) and As(V) was achieved within 54 s by the chip-CE in
G A Francis et al.
Biochemistry, 19(22), 5104-5111 (1980-10-28)
Reduction with [3H]KBH4 of Schiff's bases generated by reaction with pyridoxal 5'-phosphate (which cannot penetrate the intact cytoplasmic membrane) yields tritium-labeled derivatives of both proteins and lipids accessible on the periplasmic side of the cytoplasmic membrane. Application of this technique

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