429147

二羰基乙酰丙酮铱(I)

• 同義詞: Dicarbonyl(2,4-pentanedionato)iridium
• 線性公式: Ir(acac)(CO₂)
• CAS號碼: 14023-80-4
• 分子量：: 347.35
• MDL號碼: MFCD00049135
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24866841
• NACRES: NA.22

屬性

• 品質等級: 100
• 反應適用性: core: iridium; reagent type: catalyst
• SMILES 字串: [C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Ir]
• InChI: 1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
• InChI 密鑰: DFIAYCFHPDOZLK-FGSKAQBVSA-M

描述

應用

Catalyst for isomerization and anti-Markovnikov arylation of olefins

Reactant for:

• Oxidative addition of perfluoroalkyl iodides
• Synthesis of iridium heterocycles
• Scaffolding of iridium complexes
• Metal carbonyl cluster synthesis
• Mixed-bridged bimetallic d8 complex synthesis

安全資訊

• 象形圖: GHS08,GHS07
• 訊號詞: Warning
• 危險聲明: H302 + H312 + H332,H315,H319,H335,H361
• 防範說明: P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• 危險分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves