推薦產品
化驗
98%
形狀
liquid
折射率
n20/D 1.4685 (lit.)
bp
91-92 °C/20 mmHg (lit.)
密度
1 g/mL at 25 °C (lit.)
SMILES 字串
CC(C)(C)OC(=O)n1cccc1
InChI
1S/C9H13NO2/c1-9(2,3)12-8(11)10-6-4-5-7-10/h4-7H,1-3H3
InChI 密鑰
IZPYBIJFRFWRPR-UHFFFAOYSA-N
一般說明
N-Boc-吡咯是 N-保护的吡咯。它与对映体纯丙二烯-1,3-二羧酸酯进行 Diels-Alder 反应,形成内部加合物,在两个新生成的立体中心的保留构型。它还与苯基二乙酸甲酯进行环丙烷化,形成单环丙烷和二环丙烷。据报道,其 Ir 催化的 C-H 硼酸化,随后与 3-氯噻吩交叉偶联形成双杂环。
應用
通过用 n-BuLi 处理,随后与硼酸三甲酯反应, N-Boc-吡咯可用于合成 1-(叔丁氧基羰基)-1H-吡咯-2-基硼酸。
它可以用作以下合成中的原料:
它可以用作以下合成中的原料:
- 托品衍生物
- N-BOC-2-(4-甲氧基苯基)吡咯
- N-boc-吡咯-2-基硼酸
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
167.0 °F - closed cup
閃點(°C)
75 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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