427055

1-Boc-四氢吡咯

97%

• 同義詞: 1-吡咯烷甲酸叔丁酯
• 經驗公式（希爾表示法）: C₉H₁₇NO₂
• CAS號碼: 86953-79-9
• 分子量：: 171.24
• MDL號碼: MFCD00216581
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24866734
• NACRES: NA.22

屬性

• 化驗: 97%
• 形狀: liquid
• 折射率: n20/D 1.449 (lit.)
• bp: 80 °C/0.2 mmHg (lit.)
• 密度: 0.977 g/mL at 25 °C (lit.)
• SMILES 字串: CC(C)(C)OC(=O)N1CCCC1
• InChI: 1S/C9H17NO2/c1-9(2,3)12-8(11)10-6-4-5-7-10/h4-7H2,1-3H3
• InChI 密鑰: LPQZERIRKRYGGM-UHFFFAOYSA-N

描述

一般說明

N-Boc-pyrrolidine is an N-substituted pyrrolidine. It is reported that the reactivity of N-Boc-pyrrolidine towards C-H insertion reaction is 2000 times more than cyclohexane. It undergoes α-arylation in the presence of a palladium catalyst with high enantioselectivity.

應用

N-Boc-pyrrolidine may be used in the synthesis of the following:

• 2-aryl-N-boc-pyrrolidines
• scalemic 2-pyrrolidinylcuprates
• 2-alkenyl-N-Boc-pyrrolidines
• 1-deoxycastanospermine
• methylphenidate analogues
• (+)-elaeokanine A

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 186.8 °F - closed cup
• 閃點（°C）: 86 °C - closed cup
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter