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About This Item
線性公式:
CH3C6H3(NO2)Br
CAS號碼:
分子量：:
216.03
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級
化驗
97%
形狀
solid
bp
130 °C/12 mmHg (lit.)
mp
45-48 °C (lit.)
溶解度
water: insoluble(lit.)
官能基
bromo
nitro
SMILES 字串
Cc1ccc(Br)cc1[N+]([O-])=O
InChI
1S/C7H6BrNO2/c1-5-2-3-6(8)4-7(5)9(10)11/h2-4H,1H3
InChI 密鑰
KZNXALJXBRSMFL-UHFFFAOYSA-N
尋找類似的產品？ 前往 產品比較指南
一般說明
4-溴-2-硝基甲苯是硝基甲苯衍生物。它可以通过邻硝基甲苯的区域选择性溴化反应合成。
應用
4-溴-2-硝基甲苯可以用作以下物质合成中的起始物料：
- 4-溴-2-硝基亚苄基
- 4-溴-2-硝基苯甲醛
- 4-溴-2-氯甲苯
- 4-溴-2-硝基苯甲酸（氧化法）
- 6-溴吲哚（Batcho-Leimgruber吲哚合成）
- 3-（4-溴-2-硝基苯基）-2-[2-（叔丁基二甲基硅烷氧基）乙基]-N-（2，4-二氯-6-碘苯基）-N-甲氧基甲基丙烯酰胺
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Tyrian purple: 6, 6'-dibromoindigo and related compounds.
Cooksey CJ.
Molecules (Basel), 6(9), 736-769 (2001)
Olga V Barykina et al.
Organic letters, 12(11), 2664-2667 (2010-05-08)
The synthesis of (+/-)-eusynstyelamide A has been accomplished in six steps in 13% overall yield from 6-bromoindole, methyl glycidate, and Boc-protected agmatine. If oxygen is carefully excluded from the reaction, the key NaOH-catalyzed aldol dimerization of the alpha-ketoamide proceeded efficiently
Jae Hong Seo et al.
The Journal of organic chemistry, 71(23), 8891-8900 (2006-11-04)
An efficient synthetic strategy for installation of the two vicinal quaternary carbon centers of the communesins is reported. Key steps include the O-allylation/Claisen rearrangement of spirolactone systems, which are formed by tandem intramolecular Heck cyclization/carbonylation. Substituent and solvent effects on
The bromo-2-nitrobenzoic acids.
Erickson JLE, et al.
Journal of the American Chemical Society, 74(22), 5621-5623 (1952)
A Simple, Safe and Efficient Synthesis of Tyrian Purple (6, 6'-Dibromoindigo).
Wolk JL and Frimer AA.
Molecules (Basel), 15(8), 5561-5580 (2010)
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