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About This Item
線性公式:
(CH3)3SiC≡CI
CAS號碼:
分子量：:
224.11
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推薦產品
品質等級
化驗
97%
形狀
liquid
折射率
n20/D 1.511 (lit.)
bp
130 °C (lit.)
密度
1.46 g/mL at 25 °C (lit.)
官能基
iodo
儲存溫度
2-8°C
SMILES 字串
C[Si](C)(C)C#CI
InChI
1S/C5H9ISi/c1-7(2,3)5-4-6/h1-3H3
InChI 密鑰
HNIRHTRSZDSMOF-UHFFFAOYSA-N
應用
1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.
訊號詞
Danger
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
118.4 °F - closed cup
閃點（°C）
48 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Elodie E Marlier et al.
Inorganic chemistry, 51(4), 2079-2085 (2012-02-11)
A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine (Tol-BDI((2-pp)2)H) (1), which utilizes isopropylpyridines as pendant arms on a β-diketiminate (BDI) backbone. During the synthesis of 1, the rearrangement product, Tol-BDI((2-pp)(4-pp))H (2) was observed.
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