推薦產品
蒸汽密度
>1 (vs air)
蒸汽壓力
18 mmHg ( 20 °C)
化驗
≥99.5%
形狀
liquid
純化經由
glass distillation
redistillation
折射率
n20/D 1.435 (lit.)
pH值
10.6 (20 °C, 50 g/L)
bp
115-116 °C/750 mmHg (lit.)
mp
−66 °C (lit.)
密度
0.92 g/mL at 25 °C (lit.)
官能基
ether
SMILES 字串
CN1CCOCC1
InChI
1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3
InChI 密鑰
SJRJJKPEHAURKC-UHFFFAOYSA-N
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一般說明
4-甲基吗啉是一种经济的阳离子,可用于制备基于吗啉阳离子的离子液体。 4-甲基吗啉的实验FT-IR和FT-拉曼光谱已分别在4000-400cm-1和3500-100cm-1范围内进行测定。 它用氟化钴(III)进行氟化,可得到高度氟化的吗啉,该产物已通过质谱和NMR光谱进行表征。
應用
4-甲基吗啉可用于制备 N-乙基-N-甲基吗啉双(三氟甲磺酰基)酰亚胺。
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 1
閃點(°F)
53.6 °F - closed cup - DIN 51755 Part 1
閃點(°C)
12 °C - closed cup - DIN 51755 Part 1
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Rendell RW and Wright B.
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Ki-Sub Kim et al.
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Ionic liquids based on N-alkyl-N-methylmorpholinium salts have been synthesized and the physical and electrochemical characteristics of this family of ionic liquids have been investigated for use as electrolytes.
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V Balachandran et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1101-1110 (2012-08-30)
The experimental FT-IR (4000-400 cm(-1)) and FT-Raman (3500-100 cm(-1)) spectra of 4-Methylmorpholine were recorded. The observed bands were interpreted with the aid of normal coordinate analysis and force field calculations based on density functional theory (DFT) using B3LYP functional theory
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Teratogenesis, carcinogenesis, and mutagenesis, 19(6), 369-376 (1999-12-10)
N-methylmorpholine, which is used as a catalyst in polyurethane foams producing, in solvents, stabilizing agents, and corrosion inhibitors, was administered to female rats by gavage at 100, 200, 600, and 900 mg/kg during organogenesis. It did not exhibit selective toxicity
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