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Key Documents

379875

Sigma-Aldrich

乙酸钯(II)

99.98% trace metals basis

同義詞:

Pd(OAc)2

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About This Item

線性公式:
Pd(OCOCH3)2
CAS號碼:
分子量::
224.51
Beilstein:
6086766
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

99.98% trace metals basis

形狀

powder

反應適用性

core: aluminum
reagent type: catalyst

mp

216.3-223.7 °C (dec.)

SMILES 字串

CC(O[Pd]OC(C)=O)=O

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI 密鑰

YJVFFLUZDVXJQI-UHFFFAOYSA-L

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相關類別

應用

一种非卤化钯(II) 复合物。已被用作偶合反应的催化剂,以及作为前体用于制备非均相催化的含钯材料。

訊號詞

Danger

危險聲明

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

Lot/Batch Number

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存取文件庫

Xu, J.; et al.
Journal of Nanoparticle Research, 7 (4-5), 449-467 (2005)
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 53(44), 11895-11899 (2014-09-11)
A palladium-catalyzed dehydrogenative coupling between diarylamines and olefins has been discovered for the synthesis of substituted indoles. This intermolecular annulation approach incorporates readily available olefins for the first time and obviates the need of any additional directing group. An ortho palladation
Hu Kang et al.
Journal of the American Chemical Society, 128(18), 6194-6205 (2006-05-04)
A novel type of "X-shaped" two-dimensional electro-optic (EO) chromophore with extended conjugation has been synthesized and characterized. This chromophore is found to exhibit a remarkably blue-shifted optical maximum (357 nm in CH(2)Cl(2)) while maintaining a very large first hyperpolarizability (beta).
Palladium-catalyzed synthesis of benzofurans and coumarins from phenols and olefins.
Upendra Sharma et al.
Angewandte Chemie (International ed. in English), 52(48), 12669-12673 (2013-10-16)
Jujjuri, S.; et al.
J. Catal., 239 (2), 486-500 (2006)

文章

A variety of transition-metal catalysts for the Suzuki coupling reaction are now available in our catalog. The majority of these catalysts are palladium- and nickelbased, typically utilizing phosphine-derived ligands.

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