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Key Documents

376841

Sigma-Aldrich

3-苯基-1-丙炔

contains ca.250 ppm BHT as inhibitor, 97%

同義詞:

1-Phenyl-2-propyne, 2-Propyn-1-ylbenzene, 2-Propynylbenzene, 3-Phenylpropyne, Benzylacetylene, Propargylbenzene

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About This Item

線性公式:
C6H5CH2C≡CH
CAS號碼:
分子量::
116.16
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

品質等級

化驗

97%

形狀

liquid

包含

ca.250 ppm BHT as inhibitor

折射率

n20/D 1.526 (lit.)

bp

75 °C/20 mmHg (lit.)

密度

0.934 g/mL at 25 °C (lit.)

SMILES 字串

C#CCc1ccccc1

InChI

1S/C9H8/c1-2-6-9-7-4-3-5-8-9/h1,3-5,7-8H,6H2

InChI 密鑰

NGKSKVYWPINGLI-UHFFFAOYSA-N

一般說明

3-苯基-1-丙炔是一种 3-芳基-1-丙炔。已经通过激光诱导荧光激发和分散单电子能级荧光(SVLF)光谱研究了在 3-苯基-1-丙炔的喷射冷却放电中产生的共振稳定的 1-苯基丙炔基的电子跃迁。已经研究了 3-苯基-1-丙炔(炔丙基苯)的微波旋转光谱,据报道其稳定构型具有共面碳原子。据报道,N-甲基-N-苯基肼或 N-苯基肼与 3-苯基-1-丙炔的反应产生吲哚。据报道,3-苯基-1-丙炔与氧化苯乙烯和叠氮化钠反应生成 β-羟基三唑。

應用

3-苯基-1-丙炔可用作合成 4-苯基-2-丁炔-1-醇的起始试剂。

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

125.6 °F - closed cup

閃點(°C)

52 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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存取文件庫

Yalin Zhang et al.
Bioorganic & medicinal chemistry, 12(14), 3847-3855 (2004-06-24)
The methionine salvage pathway allows the in vivo recovery of the methylthio moiety of methionine upon the formation of methylthioadenosine (MTA) from S-adenosylmethionine (SAM). The Fe(II)-containing form of acireductone dioxygenase (ARD) catalyzes the penultimate step in the pathway in Klebsiella
Zinc-promoted hydrohydrazination of terminal alkynes: an efficient domino synthesis of indoles.
Karolin Alex et al.
Angewandte Chemie (International ed. in English), 47(12), 2304-2307 (2008-02-12)
Neil J Reilly et al.
The Journal of chemical physics, 130(14), 144313-144313 (2009-04-17)
The D(1)((2)A("))-D(0)((2)A(")) electronic transition of the resonance-stabilized 1-phenylpropargyl radical, produced in a jet-cooled discharge of 3-phenyl-1-propyne, has been investigated in detail by laser-induced fluorescence excitation and dispersed single vibronic level fluorescence (SVLF) spectroscopy.The transition is dominated by the origin band
The rotational spectrum and heavy-atom-planar structure of propargyl benzene (3-phenyl-1-propyne).
Giudici R, et al.
Journal of Molecular Structure, 786(1), 65-67 (2006)
Yadav JS, et al.
Tetrahedron Letters, 48(89), 8773-8776 (2007)

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