推薦產品
品質等級
化驗
98%
形狀
liquid
折射率
n20/D 1.406 (lit.)
bp
118-119 °C (lit.)
密度
0.762 g/mL at 25 °C (lit.)
官能基
amine
SMILES 字串
CC(C)(C)N[Si](C)(C)C
InChI
1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
InChI 密鑰
GVHIREZHTRULPT-UHFFFAOYSA-N
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一般說明
N-tert-Butyltrimethylsilylamine (Me3SiNH-t-Bu) reacts with [Cp*Rh(H2O)3](OTf)2 in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh3(μ-OH)3(μ3-OH)](OTf)3(t-BuNH3).
應用
N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.
訊號詞
Danger
危險聲明
危險分類
Flam. Liq. 3 - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
78.8 °F - closed cup
閃點(°C)
26 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Synthetic Communications, 21, 201-201 (1991)
Dalton transactions (Cambridge, England : 2003), (20)(20), 3360-3364 (2004-10-16)
Treatment of [Cp*Rh(H(2)O)(3)](OTf)(2) (1) with Me(3)SiNH-t-Bu in acetone gave a hydroxyl-capped half-cubane [Cp*(3)Rh(3)(mu-OH)(3)(mu(3)-OH)](OTf)(3)(t-BuNH(3)) (2). Slow diffusion of Me(3)SiN(3) in diethyl ether into compound in acetone produced an azido-capped half-cubane [Cp*(3)Rh(3)(mu-N(3))(3)(mu(3)-N(3))](OTf)(2) (3). On the other hand, treating 1 with Me(3)SiN(3) in
J. Solid State Inorg. Chem., 29, 759-759 (1992)
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