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367672

Sigma-Aldrich

2,2-双(4-羧基苯基)六氟丙烷

98%

同義詞:

2,2-双(4-二羧基苯基)-1,1,1,3,3,3-六氟丙烷, 2,2-双(对羧基苯基)六氟丙烷, 4,4′-[2,2,2-三氟-1-(三氟甲基)乙基亚乙基]双[苯甲酸], 4,4′-六氟异亚丙基二苯基l-1,1′-二羧酸, 4,4′-(1,1,1,3,3,3-六氟丙烷-2,2-二基)二苯甲酸, 六氟-2,2-双(4-羧基苯基)丙烷

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About This Item

線性公式:
(CF3)2C(C6H4CO2H)2
CAS號碼:
分子量::
392.25
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

mp

272-274 °C (lit.)

官能基

carboxylic acid
fluoro

SMILES 字串

OC(=O)c1ccc(cc1)C(c2ccc(cc2)C(O)=O)(C(F)(F)F)C(F)(F)F

InChI

1S/C17H10F6O4/c18-16(19,20)15(17(21,22)23,11-5-1-9(2-6-11)13(24)25)12-7-3-10(4-8-12)14(26)27/h1-8H,(H,24,25)(H,26,27)

InChI 密鑰

PHQYMDAUTAXXFZ-UHFFFAOYSA-N

一般說明

4,4′-(六氟异亚丙基)双(苯甲酸)是一种芳族二羧酸。它是一种多用途的配体。

應用

4,4′-(六氟异亚丙基)双(苯甲酸)适合用作聚恶二唑和聚三唑的合成单体。可用于:
  • 溶剂热合成带有不同过渡金属离子的新配位化合物
  • 用作金属有机配位聚合物溶剂热合成中的弯曲配体
  • 合成RPF-4(一种聚合骨架家族)

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Four new coordination compounds, namely {[Cd(3)(L)(2)(mu(3)-OH)(2)(H(2)O)] x H(2)O}(n) (1), {Ni(L)(bipy)}(n) (2), {Cu(3)(L)(2)(bipy)(mu(2)-OH)(2)(DMF)(2)}(n) (3), and {Co(2)L(2)(H(2)L)(H(2)O)}(n) (4), have been synthesized by the solvothermal reaction of 4,4'-(hexafluoroisopropylidene)bis(benzoic acid) (H(2)L) with different transition metal ions in the presence of co-ligand 4,4'-bipyridine (bipy). Compound
Wenbin Yang et al.
Inorganic chemistry, 48(23), 11067-11078 (2009-12-01)
We have synthesized five new metal-organic coordination polymers incorporating the bent ligand H(2)hfipbb [4,4'-(hexafluoroisopropylidene)bis(benzoic acid)] with different transition metal ions and co-ligands via solvothermal reactions to give [Zn(2)(hfipbb)(2)(py)(2)] x DMF (1), [Zn(2)(hfipbb)(2)(4,4'-bipy)(H(2)O)] (2), [Zn(2)(hfipbb)(2)(bpdab)].2DMF (3), [Cd(2)(hfipbb)(2)(DMF)(2)] x 2 DMF (4)
Felipe Gándara et al.
Inorganic chemistry, 48(11), 4707-4713 (2009-04-21)
RPF-4 is a family of polymeric frameworks prepared with rare-earth elements and the versatile ligand 4,4'-(hexafluoroisopropylidene)bis(benzoic acid). We have found that during the synthesis procedure up to three different polymorphs can be obtained. Their crystal structures are here presented. The

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