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359505

Sigma-Aldrich

7-甲基-1,5,7-三氮杂二环[4.4.0]癸-5-烯

98%

同義詞:

1,3,4,6,7,8-六氢-1-甲基-2H-嘧啶并[1,2-a]嘧啶, MTBD

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About This Item

經驗公式(希爾表示法):
C8H15N3
CAS號碼:
分子量::
153.22
Beilstein:
7635759
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.537 (lit.)

bp

75-79 °C/0.1 mmHg (lit.)

密度

1.067 g/mL at 25 °C (lit.)

SMILES 字串

CN1CCCN2CCCN=C12

InChI

1S/C8H15N3/c1-10-5-3-7-11-6-2-4-9-8(10)11/h2-7H2,1H3

InChI 密鑰

OEBXWWBYZJNKRK-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

一般說明

7-甲基-1,5,7-三氮杂二环[4.4.0]癸-5-烯是一种可溶性胺碱。 它与4-硝基苯基[双(二乙基磺酰基)]甲烷和苯基[双(二乙基磺酰基)]甲烷形成1:1配合物,并且已通过FT-IR、1H NMR和PM5半经验方法研究了它们的结构。 已经研究了7-甲基-1,5,7-三氮杂二环[4.4.0]癸-5-烯对菜籽油与甲醇的酯交换反应的催化性能。

應用

7-甲基-1,5,7-三氮杂二环[4.4.0]癸-5-烯可用于微波促进的、钯催化的与芳基/杂芳基九氟磺酸盐和胺的C-N键形成反应。 它可以作为强碱,用于研究多足配体溶剂、三(氧杂烷基)苯基硅烷和三(氧杂烷基)磷酸酯。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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存取文件庫

Transesterification of vegetable oils: a review.
Schuchardt U, et al.
Journal of the Brazilian Chemical Society, 9(3), 199-210 (1998)
Rachel E Tundel et al.
The Journal of organic chemistry, 71(1), 430-433 (2006-01-04)
[reaction: see text] Microwave-assisted, palladium-catalyzed C-N bond-forming reactions with aryl/heteroaryl nonaflates and amines using the soluble amine bases DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) or MTBD (7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene) and ligands (1-3) resulted in good to excellent yields (71-99%) of arylamines in short reaction times (1-45
Podand solvents for organic reactions.
Gierczyk B, et al.
Supramolecular Chemistry, 14(6), 497-502 (2002)
Spectroscopic studies of the 1: 1 complexes of 4-nitrophenyl [bis (ethylsulfonyl)] methane and phenyl [bis (ethylsulfonyl)] methane with 7-methyl-1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene and 1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene.
Huczynski A, et al.
Journal of Molecular Structure, 841(1), 133-136 (2007)
Jiun-Min Hsu et al.
PLoS genetics, 10(11), e1004715-e1004715 (2014-11-14)
Neuronal cargos are differentially targeted to either axons or dendrites, and this polarized cargo targeting critically depends on the interaction between microtubules and molecular motors. From a forward mutagenesis screen, we identified a gain-of-function mutation in the C. elegans α-tubulin

文章

The prevalence of organofluorine compounds in industry and drug design necessitates the ability to introduce C–F bonds to molecules.

The prevalence of organofluorine compounds in industry and drug design necessitates the ability to introduce C–F bonds to molecules.

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