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重要文件

345474

Sigma-Aldrich

三甲基硅醇锂

95%

同義詞:

三甲基硅烷醇 锂盐

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About This Item

線性公式:
(CH3)3SiOLi
CAS號碼:
分子量::
96.13
Beilstein:
3686900
MDL號碼:
分類程式碼代碼:
12352000
PubChem物質ID:
NACRES:
NA.22

化驗

95%

形狀

solid

SMILES 字串

[Li+].C[Si](C)(C)[O-]

InChI

1S/C3H9OSi.Li/c1-5(2,3)4;/h1-3H3;/q-1;+1

InChI 密鑰

OXOZHAWWRPCVGL-UHFFFAOYSA-N

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應用


  • 三甲基硅醇锂原子层沉积的强化工艺和组成控制。: 本研究报告了用于原子层沉积的新型锂前体三甲基硅醇锂(LiTMSO),并将其与其它锂前体进行比较,为的是改进工艺和组成控制(Ruud et al., 2017)。

  • 作为锂离子电池高电压电解质添加剂的三甲基硅氧基金属络合物: 本论文讨论了三甲基硅醇锂的合成及其作为添加剂增进高电压锂离子电池性能的用途(Imholt et al., 2017)。

  • 三甲基硅醇盐碱盐在有机合成中的应用: 本综述介绍了三甲基硅醇锂在有机合成中的各种应用,重点介绍了其在不同反应中的作用(Park et al., 2018)。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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D M Hui et al.
Clinica chimica acta; international journal of clinical chemistry, 302(1-2), 171-188 (2000-11-14)
We developed a new assay method for fluoride anion (F(-)) a specific metabolite of sarin. Trimethyifluorosilane (TMFS) was derivatized from F(-) with trimethylsilanol, and TMFS was detected with a GC-flame ionization detector (FID) and capillary column system. The linear range
A Isquith et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 26(3), 263-266 (1988-03-01)
Six organosilicon compounds which had been found to have clastogenic activity in an in vitro battery of genotoxicity assays were evaluated in rat bone marrow cytogenetic assays for assessing clastogenicity in an in vivo system. None of the six compounds
Igor S Ignatyev et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 60(5), 1169-1178 (2004-04-16)
The assignment of the SiOH group vibrations of trimethylsilanol, which is still controversial, is proposed. This assignment is based on theoretical B3LYP force field scaled using the constants of the (CH3)3Si group optimized to fit experimental vibrational frequencies of (CH3)3SiF
Fabricio A Hansel et al.
Rapid communications in mass spectrometry : RCM, 25(13), 1893-1898 (2011-06-04)
A methodology is presented for the determination of dihydroxy fatty acids preserved in the 'bound' phase of organic residues preserved in archaeological potsherds. The method comprises saponification, esterification, silica gel column chromatographic fractionation, and analysis by gas chromatography/mass spectrometry. The
Diane M Coe et al.
Organic & biomolecular chemistry, 1(7), 1106-1111 (2003-08-21)
A convenient and efficient method for the cleavage of 1,3-oxazolidin-5-ones and 1,3-oxazolidin-2-ones utilising potassium trimethylsilanolate in tetrahydrofuran is described. The benzyloxycarbonyl-protecting group is readily removed under the reaction conditions, whereas the N-benzoyl group is stable. A synthesis of (R)-salmeterol exploiting

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