341134

[1,4-双(二苯基膦)丁烷](1,5-环辛二烯)四氟硼酸铑(I)

98%

• 同義詞: [Rh(dppb)(COD)]BF4
• 經驗公式（希爾表示法）: C₃₆H₄₀BF₄P₂Rh
• CAS號碼: 79255-71-3
• 分子量：: 724.36
• MDL號碼: MFCD00075219
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24860907
• NACRES: NA.22

屬性

• 品質等級: 100
• 化驗: 98%
• 反應適用性: core: rhodium; reagent type: catalyst
• mp: 205 °C (dec.) (lit.)
• SMILES 字串: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C(CCP(c2ccccc2)c3ccccc3)CP(c4ccccc4)c5ccccc5
• InChI: 1S/C28H28P2.C8H12.BF4.Rh/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-12,15-22H,13-14,23-24H2;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;
• InChI 密鑰: YESRLRPURJQQBI-ONEVTFJLSA-N

描述

一般說明

[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium-based catalyst used for regioselective hydrogenation and enantioselective reductive amination reactions.

應用

[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I)tetrafluoroborate can be used as a catalyst for the:

• Regioselective hydrogenation of thebaine to synthesize tetrahydrothebaine.
• Enantioselective reductive amination of α-ketoacids with benzylamines to synthesize α-N-benzylamino acids.
• Stereoselective hydrogenation of α-(hydroxymethyl)-acrylate derivatives to synthesize 3-hydroxy-2-methylpropanoates.

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H302 + H312 + H332,H315,H319,H335
• 防範說明: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves