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Merck
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重要文件

326712

Sigma-Aldrich

钌黑

greener alternative

同義詞:

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About This Item

經驗公式(希爾表示法):
Ru
CAS號碼:
分子量::
101.07
EC號碼:
MDL號碼:
分類程式碼代碼:
12141739
PubChem物質ID:
NACRES:
NA.23

化驗

≥98%

形狀

powder

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

電阻係數

7.1 μΩ-cm, 0°C

表面積

17-26 m2/g

bp

3900 °C (lit.)

mp

2310 °C (lit.)

密度

12.45 g/cm3 (lit.)

環保替代類別

SMILES 字串

[Ru]

InChI

1S/Ru

InChI 密鑰

KJTLSVCANCCWHF-UHFFFAOYSA-N

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一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

應用

Ru based complexes may be used in the synthesis of anticancer drugs. Ru complexes in conjunction with magnesium may be used in the atom transfer radical addition (ATRA) and cyclization (ATRC) reactions.
Ru may be used as a catalyst in the following reactions;
  • oxidative coupling of indoles and pyrroles with several alkenes
  • arylations reactions.

包裝

Packaged in glass bottles

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

nwg

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.
Dipankar Srimani et al.
Angewandte Chemie (International ed. in English), 52(14), 4012-4015 (2013-03-08)
Bin Li et al.
The Journal of organic chemistry, 78(18), 9345-9353 (2013-09-13)
An efficient ruthenium-catalyzed oxidative coupling of indoles and pyrroles with various alkenes at the C2-position assisted by employing the N,N-dimethylcarbamoyl moiety as a directing group is reported. The catalytic reaction proceeds in an excellent regio- and stereoselective manner.
Lorraine Blackmore et al.
Chemical communications (Cambridge, England), 49(26), 2658-2660 (2013-02-26)
The targeted delivery of luminescent Ru(II) polypyridyl complexes to the nucleus of live mammalian cells by a Nuclear Localisation Signal (NLS) peptide; NF-κB is demonstrated.
M Beye et al.
Physical review letters, 110(18), 186101-186101 (2013-05-21)
We have studied the femtosecond dynamics following optical laser excitation of CO adsorbed on a Ru surface by monitoring changes in the occupied and unoccupied electronic structure using ultrafast soft x-ray absorption and emission. We recently reported [M. Dell'Angela et
Lipeng Wu et al.
Journal of the American Chemical Society, 135(10), 3989-3996 (2013-02-20)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and

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