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About This Item
線性公式:
Rh(CO)2(C5H7O2)
CAS號碼:
分子量：:
258.03
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23
推薦產品
化驗
98%
形狀
solid
反應適用性
reagent type: catalyst
mp
154-156 °C (lit.)
SMILES 字串
[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
InChI
1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
InChI 密鑰
BZCAWKOPWNIDOC-FGSKAQBVSA-M
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應用
在分子工程中用于所关注的氟溶氢甲酰化催化剂的原位形成。
訊號詞
Danger
危險分類
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Sens. 1
安全危害
儲存類別代碼
4.1B - Flammable solid hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
客戶也查看了
Horvath, I.T. et al.
Journal of the American Chemical Society, 120, 3133-3133 (1998)
K A Merchant et al.
Physical review letters, 86(17), 3899-3902 (2001-05-01)
2D spectrally resolved ultrafast (<200 fs) IR vibrational echo experiments were performed on Rh(CO)(2)acac [(acetylacetonato)dicarbonylrhodium (I)]. The 2D spectra display features that reflect the 0-1 and 1-2 transitions and the combination band transition of the symmetric (S) and antisymmetric (A)
Andrei V Pakoulev et al.
The journal of physical chemistry. A, 112(28), 6320-6329 (2008-06-25)
Triply vibrationally enhanced four-wave mixing spectroscopy is employed to observe vibrational coherence transfer between the asymmetric and symmetric CO-stretching modes of rhodium(I) dicarbonyl acetylacetonate (RDC). Coherence transfer is a nonradiative transition of a coherent superposition of quantum states to a
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