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Key Documents

277509

Sigma-Aldrich

2-辛炔酸甲酯

99%

同義詞:

Methyl heptine carbonate, NSC 72098

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About This Item

線性公式:
CH3(CH2)4C≡CCO2CH3
CAS號碼:
分子量::
154.21
Beilstein:
1756887
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.446 (lit.)

bp

217-220 °C (lit.)

密度

0.92 g/mL at 25 °C (lit.)

官能基

ester

SMILES 字串

CCCCCC#CC(=O)OC

InChI

1S/C9H14O2/c1-3-4-5-6-7-8-9(10)11-2/h3-6H2,1-2H3

InChI 密鑰

FRLZQXRXIKQFNS-UHFFFAOYSA-N

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一般說明

Methyl 2-octynoate has been quantitated as suspected allergen in cosmetic products by headspace-programmed temperature vaporization-fast gas chromatography-quadrupole mass spectrometry. It participates in nickel-catalyzed carbocyclization of 2-iodoacetophenone to yield a 2,3-disubstituted indenol.

象形圖

Exclamation markEnvironment

訊號詞

Warning

危險聲明

危險分類

Aquatic Acute 1 - Aquatic Chronic 3 - Skin Sens. 1A

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

192.2 °F - closed cup

閃點(°C)

89 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Miguel del Nogal Sánchez et al.
Analytical and bioanalytical chemistry, 397(6), 2579-2591 (2010-05-25)
In the present work, a strategy for the qualitative and quantitative analysis of 24 volatile compounds listed as suspected allergens in cosmetics by the European Union is reported. The list includes benzyl alcohol, limonene, linalool, methyl 2-octynoate, beta-citronellol, geraniol, citral
Dinesh Kumar Rayabarapu et al.
Chemical communications (Cambridge, England), (9)(9), 942-943 (2002-07-19)
Carbocylization of o-halophenyl ketones with propiolates in the presence of Ni(dppe)Br2 and Zn powder in acetonitrile at 80 degrees C afforded the corresponding 2,3-disubstituted indenols.
I Takanami et al.
Gan no rinsho. Japan journal of cancer clinics, 30(4), 340-343 (1984-04-01)
Results of methyl heptine carbonate skin tests were compared with DNCB skin test results in 155 patients with chest diseases. Reactions to methyl heptine carbonate and DNCB were similar in 142 of 155 patients (92%). Forty-two lung cancer patients and
Jurij J Hostynek et al.
Cutaneous and ocular toxicology, 25(4), 259-271 (2006-12-13)
The fragrance material methyl heptine carbonate has been cited as a moderately frequent cause of cosmetics-related allergic contact dermatitis. A review of the literature shows that when the underlying clinical data are analyzed, there is only one published case where
[Cutaneous delayed hypersensitivity to methyl hepatine carbonate in pulmonary tuberculosis].
I Takanami
Nihon Kyobu Shikkan Gakkai zasshi, 24(10), 1066-1070 (1986-10-01)

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