264679

2,6,6-三甲基-1-环己烯基乙醛

technical grade, 80%

• 同義詞: β-环高柠檬醛
• 經驗公式（希爾表示法）: C₁₁H₁₈O
• CAS號碼: 472-66-2
• 分子量：: 166.26
• EC號碼: 207-454-0
• MDL號碼: MFCD00012057
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24856029
• NACRES: NA.22

屬性

• 等級: technical grade
• 品質等級: 100
• 化驗: 80%
• 形狀: liquid
• 折射率: n20/D 1.485 (lit.)
• bp: 58-59 °C/0.4 mmHg (lit.)
• 密度: 0.941 g/mL at 25 °C (lit.)
• 官能基: aldehyde
• SMILES 字串: [H]C(=O)CC1=C(C)CCCC1(C)C
• InChI: 1S/C11H18O/c1-9-5-4-7-11(2,3)10(9)6-8-12/h8H,4-7H2,1-3H3
• InChI 密鑰: VHTFHZGAMYUZEP-UHFFFAOYSA-N

描述

應用

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde can be used as a starting material to prepare:

• (±)-Aeginetolide by oxidation in the presence of meta-chloroperoxybenzoic acid (m-CPBA).
• (±)-Dihydroactinidiolide (a C₁₁-terpenic lactone) via dehydration of key intermediate aeginetolide.

It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.

其他說明

含有 β-环柠檬醛

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 10 - Combustible liquids
• 水污染物質分類（WGK）: WGK 3
• 個人防護裝備: Eyeshields, Gloves, type ABEK (EN14387) respirator filter