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Merck
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重要文件

258202

Sigma-Aldrich

四氯化铪

98%

同義詞:

Hafnium tetrachloride, Tetrachlorohafnium

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About This Item

線性公式:
HfCl4
CAS號碼:
分子量::
320.30
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

等級

for analytical purposes

蒸汽壓力

1 mmHg ( 190 °C)

化驗

98%

形狀

powder

mp

432 °C (lit.)

溶解度

H2O: decomposes(lit.)

SMILES 字串

Cl[Hf](Cl)(Cl)Cl

InChI

1S/4ClH.Hf/h4*1H;/q;;;;+4/p-4

InChI 密鑰

PDPJQWYGJJBYLF-UHFFFAOYSA-J

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一般說明

氯化铪,又名四氯化铪,常用作前体生产铪金属和各种铪化合物。还用作某些有机合成反应的催化剂。因其反应性和湿度敏感性,氯化铪通常在惰性环境中处理。

應用

氯化铪用处:     
  • 作为前体合成磷酸铪锂,因其高离子导电性和化学稳定性而用作锂电池的固态电解质材料。      
  • 作为催化剂用于各种羰基化合物(包括醛和酮)的缩醛化反应。      
  • 作为催化剂用于羧酸与醇的直接酯化缩合反应。    
  • 作为锂和钠离子电池的高容量正极材料。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3


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Direct condensation of carboxylic acids with alcohols catalyzed by hafnium (IV) salts.
Ishihara K, et al.
Science, 290.5494, 1140-1142 (2000)
Visualization of the cytoskeletal elements in tissue culture cells by bloc-staining with hafnium chloride after rapid freezing and freeze-substitution fixation.
T Hatae et al.
Journal of electron microscopy, 33(2), 186-190 (1984-01-01)
Guoguang Liu et al.
Biomacromolecules, 9(3), 949-953 (2008-02-15)
The feasibility of a previously established method based on ozonolysis and hydrogenation reactions for the production of 9-hydroxynonanoic acid from oleic acid has been demonstrated. Metal catalyzed lactonization conditions have been used to convert 9-hydroxynonanoic acid into 1,11-dioxacycloicosane-2,12-dione, which is
Lutz Ackermann et al.
Organic & biomolecular chemistry, 5(12), 1975-1978 (2007-06-07)
Two distinct economical catalysts for intramolecular hydroaminations of electronically unactivated alkenes with basic amines are described, which are based on (a) group 4 metal halides under basic reaction conditions or (b) Brønsted-acid organocatalysts.

文章

In the last two decades, a new method termed solid-state metathesis (SSM) has been developed to synthesize compounds that are often difficult to produce conventionally.

In the last two decades, a new method termed solid-state metathesis (SSM) has been developed to synthesize compounds that are often difficult to produce conventionally.

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