257885

三甲基硅基环戊二烯，异构体混合物

• 同義詞: NSC 176274
• 經驗公式（希爾表示法）: C₈H₁₄Si
• CAS號碼: 3559-74-8
• 分子量：: 138.28
• MDL號碼: MFCD00010666
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24855613
• NACRES: NA.22
• 形狀: liquid

屬性

• 形狀: liquid
• 品質等級: 200
• 折射率: n20/D 1.471 (lit.)
• bp: 138-140 °C (lit.)
• 密度: 0.833 g/mL at 25 °C (lit.)
• 儲存溫度: −20°C
• SMILES 字串: C[Si](C)(C)C1C=CC=C1
• InChI: 1S/C8H14Si/c1-9(2,3)8-6-4-5-7-8/h4-8H,1-3H3
• InChI 密鑰: VMFHCJPMKUTMMQ-UHFFFAOYSA-N

描述

一般說明

Trimethylsilyl cyclopentadiene reacts with ruthenium trichloride in alcohol solvent to yield ruthenocene.

應用

Reactant involved in:

• Diels-Alder reactions
• Synthesis of ring-functionalized molybdenocene complexes
• Allyl isomerization
• Aromatization of C5 rings
• Synthesis of N-hydroxyindoles via nucleophilic addition

安全資訊

• 象形圖: GHS02,GHS07
• 訊號詞: Warning
• 危險聲明: H226,H315,H319,H335
• 防範說明: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 84.2 °F - closed cup
• 閃點（°C）: 29 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter