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Merck
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Key Documents

253871

Sigma-Aldrich

1-壬炔

99%

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About This Item

線性公式:
CH3(CH2)6C≡CH
CAS號碼:
分子量::
124.22
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

16 mmHg ( 37.7 °C)

品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.422 (lit.)

bp

150-151 °C (lit.)

mp

−50 °C (lit.)

密度

0.757 g/mL at 25 °C (lit.)

SMILES 字串

CCCCCCCC#C

InChI

1S/C9H16/c1-3-5-7-9-8-6-4-2/h1H,4-9H2,2H3

InChI 密鑰

OSSQSXOTMIGBCF-UHFFFAOYSA-N

一般說明

1-Nonyne reacts with thianthrene cation radical tetrafluoroborate to form trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate.

應用

1-Nonyne has been used in enantioselective synthesis of cladospolide B, C and (ent)-cladospolide D.

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

93.2 °F - closed cup

閃點(°C)

34 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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客戶也查看了

Paramashivappa Rangappa et al.
The Journal of organic chemistry, 70(24), 9764-9770 (2005-11-19)
[structure: see text] Thianthrene cation radical tetrafluoroborate (Th*+ BF4(-)) added to the terminal alkynes 1-pentyne, 1-hexyne, 1-heptyne, 1-octyne, 1-nonyne, and 1-decyne to form trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborates (1-6). Similarly, addition of phenoxathiin cation radical tetrafluoroborate (PO*+ BF4(-)) to the same alkynes gave
Yalan Xing et al.
Organic letters, 11(5), 1107-1110 (2009-02-06)
The enantioselective synthesis of cladospolide B, C, and (ent)-cladospolide D has been achieved in 11-15 steps from 1-nonyne. The route relies upon an alkyne zipper reaction to relay an ynone and dienoate functional groups across a nine carbon fragment, which

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