推薦產品
等級
reagent grade
化驗
98%
形狀
crystals
反應適用性
core: bismuth
reagent type: catalyst
bp
75-80 °C (lit.)
mp
30 °C (lit.)
SMILES 字串
O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
InChI
1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1
InChI 密鑰
DPLOIMSBRDLLRI-UHFFFAOYSA-N
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一般說明
硝酸铋(III) 五水合物是水合形式的硝酸铋(III)。它可作为有效的路易斯酸催化剂用于硫代羰基转化为羰基化合物的有机合成反应;芳香硝化反应;羰基化合物的保护;Michael反应和香豆素的合成。
應用
各种 4-取代的 Hantzsch 1,4-二氢吡啶的优质氧化剂。将硫化物选择性氧化成亚砜的简便试剂。
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Ox. Sol. 2
儲存類別代碼
5.1B - Oxidizing hazardous materials
水污染物質分類(WGK)
WGK 2
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Two bismuth(III) porphyrins-5,10,15,20-tetrakis(phenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(TPP)]NO3, and the unprecedent 5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(T4CMPP)]NO3, and two unprecedented antimony(V) porphyrins dichlorido(5,10,15,20-tetrakis(phenyl)porphyrinato)antimony(V) bromide, [Sb(V)(TPP)Cl2]Br, and dibromido(5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinato)antimony(V) bromide, [Sb(V)(T4CMPP)Br2]Br,-were synthesized by reacting the corresponding porphyrin ligand with Bi(NO3)3·5H2O or SbCl3. All compounds were characterized by UV-vis
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