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重要文件

203548

Sigma-Aldrich

硝酸镧(III) 六水合物

99.999% trace metals basis

同義詞:

硝酸,镧(III)盐,六水合物

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About This Item

線性公式:
La(NO3)3 · 6H2O
CAS號碼:
分子量::
433.01
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

99.999% trace metals basis

形狀

solid

反應適用性

reagent type: catalyst
core: lanthanum

雜質

≤15.0 ppm Trace Rare Earth Analysis

mp

65-68 °C

SMILES 字串

[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

InChI 密鑰

GJKFIJKSBFYMQK-UHFFFAOYSA-N

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一般說明

硝酸镧六水合物是过渡金属催化剂,广泛用于许多有机转化反应,例如丙酮化合物的化学选择性脱保护,醇、酚和胺与乙酸酐的酰化,α-氨基腈类化合物的合成反应。也可作为前体制备镧基纳米粒子。

應用

硝酸镧六水合物可用作下列反应的催化剂:
  • α羰基化合物、胺类和TMSCN通过一锅三组分偶联作用合成α-氨基腈。
  • 醛合成缩醛和偕二乙酸酯(乙酰缩醛)。
  • 无溶剂条件合成双吲哚基甲烷。
也可用作起始原料,用于电化学合成LaMnO3薄膜和溶剂热法合成掺杂型硫氧化镧(La2O2S)。

特點和優勢

  • 热稳定性
  • 低毒
  • 反应条件温和
  • 化学选择性
  • 低成本

訊號詞

Danger

危險聲明

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 2

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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X Hua et al.
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Xiao-Wu Wang et al.
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文章

The prevailing strategies for heat and electric-power production that rely on fossil and fission fuels are having a negative impact on the environment and on our living conditions.

The rare earth elements impact nearly everyone in the world. All of the people living in advanced technological countries and almost all those living in third world countries utilize the rare earths in their everyday living—the car that one drives (gasoline is refined from oil using rare earth catalysts and catalytic converters reduce the polluting emissions from the automotive exhaust), watching the news on TV (the red and green colors in TV screens), the telephones and computers we use to communicate (the permanent magnets in speakers and disc drives), just to name a few examples.

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

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