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Merck
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重要文件

196657

Sigma-Aldrich

1-氟萘

99%

同義詞:

α-氟萘

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About This Item

經驗公式(希爾表示法):
C10H7F
CAS號碼:
分子量::
146.16
Beilstein:
1906413
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.593 (lit.)

bp

215 °C (lit.)

mp

−13 °C (lit.)

密度

1.1322 g/mL at 20 °C (lit.)

官能基

fluoro

SMILES 字串

Fc1cccc2ccccc12

InChI

1S/C10H7F/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI 密鑰

CWLKTJOTWITYSI-UHFFFAOYSA-N

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一般說明

研究了 O 2 和 1-氟萘混合物在气相中的闪光光解反应

應用

1-氟萘用于 t -BuLi 介导的 6-取代菲啶的合成 。它也被用于合成 LY248686,一种 5-羟色胺和去甲肾上腺素摄取的强效抑制剂

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

149.0 °F - closed cup

閃點(°C)

65 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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Asymmetric synthesis and absolute stereochemistry of LY248686.
Deeter J, et al.
Tetrahedron Letters, 31(49), 7101-7104 (1990)
Jan Pawlas et al.
Organic letters, 4(16), 2687-2690 (2002-08-03)
[reaction: see text] A one-pot, t-BuLi-induced synthesis of 6-substituted phenanthridines from fluoroarenes and nitriles via 1,2-arynes is reported. Aryl- and hetaryl nitriles, cyanamides, and trimethylacetonitrile gave phenanthridine products. The method was extended to provide bisphenanthridine 10 by a one-pot bis-cyclization
Formation of O 2 (1Sigma g+) by 1-fluoronaphthalene sensitization.
Andrews LJ and Abrahamson EW.
Chemical Physics Letters, 10, 113-116 (1971)
C E Cerniglia et al.
Applied and environmental microbiology, 48(2), 294-300 (1984-08-01)
The metabolism of 1-fluoronaphthalene by Cunninghamella elegans ATCC 36112 was studied. The metabolites were isolated by reverse-phase high-pressure liquid chromatography and characterized by the application of UV absorption, 1H nuclear magnetic resonance, and mass spectral techniques. C. elegans oxidized 1-fluoronaphthalene
Peter Wipf et al.
Organic letters, 5(7), 1155-1158 (2003-03-28)
[reaction: see text] Electron-rich dinaphthyl ethers were synthesized by S(N)Ar reactions between naphthols and activated fluoronaphthalenes. 2-tert-Butyl-1,1,3,3-tetramethylguanidine (Barton's base) was found to be an excellent, mild alternative to traditional inorganic bases for promoting the coupling reaction.

條款

US EPA Method 610 describes the analysis of polynuclear aromatic hydrocarbons (commonly referred to as PAHs or PNAs) by both HPLC and GC.

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