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187186

Sigma-Aldrich

肉桂基氯

95%

同義詞:

3-苯基丙烯基氯

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About This Item

線性公式:
C6H5CH=CHCH2Cl
CAS號碼:
分子量::
152.62
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

95%

形狀

liquid

折射率

n20/D 1.584 (lit.)

bp

108 °C/12 mmHg (lit.)

mp

−19 °C (lit.)

密度

1.096 g/mL at 25 °C (lit.)

官能基

chloro
phenyl

儲存溫度

2-8°C

SMILES 字串

ClC\C=C\c1ccccc1

InChI

1S/C9H9Cl/c10-8-4-7-9-5-2-1-3-6-9/h1-7H,8H2/b7-4+

InChI 密鑰

IWTYTFSSTWXZFU-QPJJXVBHSA-N

一般說明

在钯催化剂存在下,肉桂酰氯与芳基和烯基金 (I) 膦烷在 THF 中发生区域选择性反应,得到 α-取代产物 †。

應用

肉桂酰氯用于不对称全合成具有生物活性的海洋二萜化合物——氦孔蛋白 C 和 E

象形圖

Health hazardExclamation mark

訊號詞

Warning

危險分類

Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1B - STOT RE 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

174.2 °F - closed cup

閃點(°C)

79 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Wibke Lölsberg et al.
Organic letters, 14(23), 5996-5999 (2012-11-15)
A short and enantioselective total synthesis of helioporins C and E, which are bioactive marine diterpenes containing a serrulatane or amphilectane skeleton, was elaborated. The chirogenic step, i.e. a Cu(I)-catalyzed allylic alkylation of a cinnamyl chloride with methylmagnesium bromide, proceeded
Juan Carlos Rueda et al.
Polymers, 12(6) (2020-06-26)
Stiff thermosensitive hydrogels (HG) were synthesized by self-crosslinking free radical polymerization of N,N-dimethylacrylamide (DMAA) and N-isopropylacrylamide (NIPAAm), adjusting the degree of swelling by carboxylate-containing sodium acrylate (NaAc) or a 2-oxazoline macromonomer (MM). The formation of hydrogels was possible due to
Miguel Peña-López et al.
Organic & biomolecular chemistry, 10(8), 1686-1694 (2012-01-24)
Aryl and alkenylgold(I) phosphanes react regioselectively with allylic electrophiles such as cinnamyl and geranyl halides (bromide, chloride and acetates) under palladium catalysis in THF at 80 °C to afford the α-substitution product with moderate to high yields. When the reaction

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