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Key Documents

28115

Sigma-Aldrich

巴豆基氯

technical, (cis+trans), mixture of cis- and trans-isomers (~1:6), ~70% (GC)

同義詞:

1-氯-2-丁烯(顺反异构体混合物)

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About This Item

線性公式:
CH3CH=CHCH2Cl
CAS號碼:
分子量::
90.55
Beilstein:
605304
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

等級

technical

化驗

~70% (GC)

形狀

liquid

雜質

~30% 3-chloro-1-butene

折射率

n20/D 1.430

bp

85-86 °C (lit.)

溶解度

water: soluble 14 g/L at 20 °C

密度

0.923 g/mL at 20 °C (lit.)

官能基

alkyl halide
chloro

SMILES 字串

C\C=C\CCl

InChI

1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+

InChI 密鑰

YTKRILODNOEEPX-NSCUHMNNSA-N

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一般說明

Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes.

應用

Crotyl chloride has been used:
  • to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
  • in the preparation of (E)-crotyltrichlorosilane

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Skin Sens. 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

10.4 °F - closed cup

閃點(°C)

-12 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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The condensation reaction of trichlorosilane with allylic chlorides catalyzed by copper salts in the presence of a tertiary amine.
Furuya N and Sukawa T.
Journal of Organometallic Chemistry, 96(1), C1-C3 (1975)
Rate constants for the reactions of chlorine atoms with a series of unsaturated aldehydes and ketones at 298 K: structure and reactivity.
Wang W, et al.
Physical Chemistry Chemical Physics, 4(10), 1824-1831 (2002)
Stereohomogeneous synthesis of (E)-and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydes.
Kira M, et al.
Tetrahedron Letters, 30(9), 1099-1102 (1989)

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