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About This Item
線性公式:
SiHCl3
CAS號碼:
分子量：:
135.45
EC號碼:
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22
推薦產品
蒸汽密度
1 (vs air)
品質等級
蒸汽壓力
9.75 psi ( 20 °C)
化驗
99%
形狀
liquid
expl. lim.
70 %
bp
32-34 °C (lit.)
密度
1.342 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
Cl[SiH](Cl)Cl
InChI
1S/Cl3HSi/c1-4(2)3/h4H
InChI 密鑰
ZDHXKXAHOVTTAH-UHFFFAOYSA-N
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一般說明
三氯硅烷可用作某些化学反应的还原剂，或作为起始材料合成各种有机硅化合物。三氯硅烷通常用于烯烃在钯催化剂存在下与手性单齿磷配体配位的不对称硅氢加成反应，生成手性有机硅烷。
應用
以三氯氢硅为原料，通过还原 11-二环己基膦酰-12-苯基-9,10-二氢-9,10-乙烯蒽，合成了 11-二环己基膦-12-苯基-9,10-二氢-9,10-乙烯蒽。
其他可能的应用：
L -缬氨酸衍生物催化剂存在下 N -芳基酮亚胺的不对称还原形成仲胺。
衍生物活化的三氯硅烷是亚胺还原生成
对映体富集胺的有效试剂。
其他可能的应用：
- 在新型
L -缬氨酸衍生物催化剂存在下 N -芳基酮亚胺的不对称还原形成仲胺。
- 在 2,2′ 存在下咪唑啉酮硅氢化形成手性咪唑烷酮类化合物-双吡咯烷基路易斯碱有机催化剂。
- 手性 N -甲酰脯氨酸
衍生物活化的三氯硅烷是亚胺还原生成
对映体富集胺的有效试剂。
- 三氯氢硅与二甲基甲酰胺反应生成高价氢硅酸盐，后者可将醛还原为醇类，亚胺还原为胺类，也可用于醛的还原胺化。
訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 1
閃點（°F）
<-2.2 °F - Equilibrium method
閃點（°C）
< -19 °C - Equilibrium method
個人防護裝備
Faceshields, Gloves, Goggles
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