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About This Item
線性公式:
TlOC2H5
CAS號碼:
分子量：:
249.44
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.22
推薦產品
形狀
liquid
品質等級
反應適用性
core: thallium
reagent type: catalyst
折射率
n20/D 1.676 (lit.)
密度
3.522 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
CCO[Tl]
InChI
1S/C2H5O.Tl/c1-2-3;/h2H2,1H3;/q-1;+1
InChI 密鑰
DZFYOYRNBGNPJW-UHFFFAOYSA-N
應用
用HCl还原各种官能团；羰基化合物的立体选择性烯丙基化；原位生成锡烯醇化物用于定向羟醛反应。
訊號詞
Danger
危險分類
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
235.4 °F - closed cup
閃點（°C）
113 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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The reaction of thallium ethoxide with [H(OEt2)2][H2N{B(C6F5)3}2] in diethyl ether afforded [Tl(OEt2)3][H2N{B(C6F5)3}2] (2a), [Tl(OEt2)4][H2N{B(C6F5)3}2] (2b), or [Tl(OEt2)2][H2N{B(C6F5)3}2].CH2Cl2 (2c), depending on the reaction conditions. The dication in the hydrolysis product [Tl4(mu3-OH)2][H2N{B(C6F5)3}2]2.4CH2Cl2 consists of two bridging and two terminal Tl+ ions bound
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