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143650

Sigma-Aldrich

5H-二苯并[b,f]氮杂

97%

同義詞:

亚氨基芪

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About This Item

經驗公式(希爾表示法):
C14H11N
CAS號碼:
分子量::
193.24
Beilstein:
1343358
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

mp

196-199 °C (lit.)

溶解度

ethyl acetate: soluble 25 mg/mL, clear, yellow to orange

SMILES 字串

N1c2ccccc2C=Cc3ccccc13

InChI

1S/C14H11N/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)15-13/h1-10,15H

InChI 密鑰

LCGTWRLJTMHIQZ-UHFFFAOYSA-N

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一般說明

5H-二苯并[b,f]吖庚因是一种具有七元环的三环类胺,常称为亚氨基芪。它可用作合成多种抗痉挛药物的中间体或起始材料。

應用

5H-二苯并[b,f]氮杂卓可用于:
  • 作为原料制备重要的二苯并氮杂卓-哒嗪衍生物。
  • 合成氨基苯酚衍生物制备中的关键中间体 3-氯-1-(5H-二苯并[b,f]氮杂卓-5基)丙烷-1-酮。
  • 合成二苯并氮杂卓衍生物。
  • 作为原料合成用于制备铑(I)配合物的烯类多齿配体。

生化/生理作用

2-(溴甲基)萘是一种荧光烷基溴。它通过酶水解使聚对苯二甲酸乙二醇酯表面形成的游离羧基酯化。它在P4S10/酰基胞苷反应中充当有机亲电子试剂。

象形圖

Exclamation markEnvironment

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


分析證明 (COA)

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Synthesis and Calorimetry of Some Derivatives of Dibenzazepine
Analytical Calorimetry (1970)
Synthesis and Calorimetry of Some Derivatives of Dibenzazepine.
Gipstein E, et al.
Analytical Calorimetry, 127-134 (1970)
Kuppuswamy Arumugam et al.
Inorganic chemistry, 46(8), 3283-3288 (2007-03-16)
The reaction of P4S10 with acyloins, RC(O)CH(OH)R, in refluxing dioxane, followed by the addition of alkylating agents, forms dithiolene thiophosphoryl thiolate compounds, (R2C2S2)P(S)(SR'), which are readily isolated and purified. The compounds that have been prepared and identified spectroscopically are those
S M Furst et al.
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A Varenne et al.
Journal of immunological methods, 186(2), 195-204 (1995-10-26)
As part of our ongoing work to extend the range of applications of the non-isotopic carbonyl metalloimmunoassay (CMIA), previously developed in our laboratory, we describe here the first CMIA study of carbamazepine. The CMIA method uses a metal carbonyl complex

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