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About This Item
線性公式:
C6H5CH2NC
CAS號碼:
分子量：:
117.15
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推薦產品
品質等級
化驗
98%
折射率
n20/D 1.521 (lit.)
bp
105-106 °C/75 mmHg (lit.)
密度
0.962 g/mL at 25 °C (lit.)
官能基
amine
isonitrile
phenyl
儲存溫度
−20°C
SMILES 字串
[C-]#[N+]Cc1ccccc1
InChI
1S/C8H7N/c1-9-7-8-5-3-2-4-6-8/h2-6H,7H2
InChI 密鑰
RIWNFZUWWRVGEU-UHFFFAOYSA-N
一般說明
苄基异腈形成含磷杂烯的复合物 。
應用
苄基异氰用于合成含有肼和苄基异氰配体的 Ru (II) 配合物 。它被用于一个三组分耦合过程，得到 O -和 N -芳基酰胺 。
其他說明
储存时颜色可变暗
訊號詞
Warning
危險分類
Acute Tox. 4 Oral
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
174.2 °F - closed cup
閃點（°C）
79 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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The use of Smiles rearrangement in Ugi- and Passerini-type couplings with electron-deficient phenols allows very straightforward multicomponent formation of O-aryl- and N-arylamides. Best yields were observed with the highly activated o- and p-nitrophenols, salicylic derivatives giving adducts in lower yields.
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Iranian journal of pharmaceutical research : IJPR, 19(3), 134-143 (2021-03-09)
The complex [(PhCH2NC)AuCl], 1, was prepared by the reaction of [(Me2S)AuCl], A, with an equimolar amount of benzyl isocyanide (PhCH2NC) ligand. Through a salt metathesis reaction, the chloride ligand in 1 was replaced by potassium benzothiazole-2-thiolate (Kbt) and potassium benzoimidazole-2-thiolate
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Chemical science, 10(20), 5235-5245 (2019-06-14)
We report the formation of a series of novel [Ir(H)2(IMes)(α-13C2-carboxyimine)L] complexes in which the identity of the coligand L is varied. When examined with para-hydrogen, complexes in which L is benzylamine or phenethylamine show significant 1H hydride and 13C2 imine
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