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Merck
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126721

Sigma-Aldrich

氢化偶氮苯

同義詞:

1,2-二苯肼, NSC 3510

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About This Item

線性公式:
C6H5NHNHC6H5
CAS號碼:
分子量::
184.24
Beilstein:
639793
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

形狀

solid

mp

123-126 °C (lit.)

SMILES 字串

N(Nc1ccccc1)c2ccccc2

InChI

1S/C12H12N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10,13-14H

InChI 密鑰

YBQZXXMEJHZYMB-UHFFFAOYSA-N

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一般說明

氢化偶氮苯是氧化偶氮苯氢化成苯胺的中间体
通过在 THF 中用 SmI(2)还原偶氮苯来制备氢化偶氮苯

應用

作为以下反应的反应物:
  • 与有机金属钽配合物发生的插入反应
  • 三氯化钛(III)催化的还原反应,生成胺
  • 研究苯重排的机理
  • N-杂环稳定的甲硅烷基发生的反应
  • 二锰酰胺酰肼簇合物的合成
  • 铁介导的肼还原反应,生成亚芳基铁立方烷

其他說明

含有不定量的偶氮苯

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


分析證明 (COA)

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Darol E Dodd et al.
International journal of toxicology, 31(6), 564-571 (2012-11-09)
Male F344 rats were exposed to hydrazobenzene (HZB) by dietary feed at concentrations of 0, 5, 20, 80, 200, or 300 ppm for 5 days, 2 weeks, 4 weeks, or 13 weeks duration. End points evaluated included clinical observations, body
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Report on carcinogens : carcinogen profiles, 10, 139-140 (2004-08-26)
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Journal of pharmaceutical sciences, 73(12), 1706-1709 (1984-12-01)
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Jenny V Lockard et al.
The journal of physical chemistry. A, 109(6), 1205-1215 (2006-07-13)
A quantitative model of mixed-valence excited-state spectroscopy is developed and applied to 2,3-diphenyl-2,3-diazabicyclo[2.2.2]octane. The lowest-energy excited state of this molecule arises from a transition from the ground state, where the charge is located on the hydrazine bridge, to an excited

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