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Key Documents

124087

Sigma-Aldrich

2-溴-4-甲基苯胺

98%

同義詞:

2-溴-对甲苯胺, 4-氨基-3-溴甲苯

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About This Item

線性公式:
BrC6H3(CH3)NH2
CAS號碼:
分子量::
186.05
Beilstein:
1931711
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.602 (lit.)

bp

240 °C (lit.)

mp

14-16 °C (lit.)

密度

1.5 g/mL at 25 °C (lit.)

SMILES 字串

Cc1ccc(N)c(Br)c1

InChI

1S/C7H8BrN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3

InChI 密鑰

UVRRJILIXQAAFK-UHFFFAOYSA-N

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一般說明

2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide.

應用

2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

230.0 °F - closed cup

閃點(°C)

110 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Synthesis and reactivity of ortho-palladated arylcarbodiimides and aryl isothiocyanates. Formation of C-palladated quinazolines. Synthesis of 2-aminoquinolines.
Vicente J, et al.
Organometallics, 23(20), 4711-4722 (2004)
Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation.
Koubachi J, et al.
Tetrahedron, 66(10), 1937-1946 (2010)
Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation.
Hostyn S, et al.
Tetrahedron, 62(19), 4676-4684 (2006)

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