163155

Ethyl trichloroacetate

97%

• Linear Formula: Cl₃CCO₂CH₂CH₃
• CAS Number: 515-84-4
• Molecular Weight: 191.44
• Beilstein: 1761567
• EC Number: 208-212-7
• MDL number: MFCD00000795
• UNSPSC Code: 12352100
• PubChem Substance ID: 24850025
• NACRES: NA.22

Properties

• Assay: 97%
• refractive index: n20/D 1.453 (lit.)
• bp: 168 °C (lit.)
• solubility: alcohol: miscible(lit.); diethyl ether: miscible(lit.); water: insoluble(lit.)
• density: 1.378 g/mL at 25 °C (lit.)
• SMILES string: CCOC(=O)C(Cl)(Cl)Cl
• InChI: 1S/C4H5Cl3O2/c1-2-9-3(8)4(5,6)7/h2H2,1H3
• InChI key: SJMLNDPIJZBEKY-UHFFFAOYSA-N

Description

General description

Ethyl trichloroacetate undergoes atom-transfer radical addition reaction with styrene catalyzed by the Ru-pentamethylcyclopentadienyl complexes.

Application

Ethyl trichloroacetate was used in the synthesis of dichlorocarbon precursor, phenyl(trichloromethyl)methyl.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302,H315
• Precautionary Statements: P264 - P280 - P301 + P312 - P302 + P352 - P332 + P313 - P362 + P364
• Hazard Classifications: Acute Tox. 4 Oral - Skin Irrit. 2
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 1
• Flash Point(F): 163.4 °F - closed cup
• Flash Point(C): 73 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves