900275
(t-Bu)PhCPhos
95%
Synonym(s):
2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl
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About This Item
Empirical Formula (Hill Notation):
C26H33N2P
CAS Number:
Molecular Weight:
404.53
UNSPSC Code:
12352200
NACRES:
NA.22
Quality Level
Assay
95%
form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand
mp
112 °C
functional group
phosphine
Application
(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Paula Ruiz-Castillo et al.
Journal of the American Chemical Society, 137(8), 3085-3092 (2015-02-05)
We report the Pd-catalyzed arylation of very hindered α,α,α-trisubstituted primary amines. Kinetics-based mechanistic analysis and rational design have led to the development of two biarylphosphine ligands that allow the transformation to proceed with excellent efficiency. The process was effective in
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