661023

Hydroxy(cyclooctadiene)rhodium(I) dimer

95%

• Synonym(s): (Cyclooctadiene)rhodium hydroxide dimer, 1,5-Cyclooctadiene)hydroxyrhodium dimer, Bis(cyclooctadiene)dihydroxodirhodium, Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di--μ-hydroxydirhodium, Bis[(1,5-cyclooctadiene)(hydroxy)rhodium], [Rh(OH)(1,5-cod)]₂
• Empirical Formula (Hill Notation): C₁₆H₂₆O₂Rh₂
• CAS Number: 73468-85-6
• Molecular Weight: 456.19
• MDL number: MFCD08457638
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884496
• NACRES: NA.22

Properties

• Assay: 95%
• form: solid
• reaction suitability: core: rhodium; reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 199 °C (dec.)
• greener alternative category: Aligned,
• SMILES string: O[Rh].O[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2H2O.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H2;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
• InChI key: IUAQXTGDGDIMOD-MIXQCLKLSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Efficient and Selective Catalysts for Asymmetric Synthesis

Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Rhodium catalyst employed with R-BINAP or R-SEGPHOS^® ligands in a synthesis of chiral 3,3-disubstituted-1-indanones.

Legal Information

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves