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Titanium(IV) fluoride

Name: Titanium(IV) fluoride
Brand: ALDRICH

Synonym(s):

Titanium tetrafluoride, Titanium fluoride

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About This Item

Linear Formula:

TiF₄

CAS Number:

7783-63-3

Molecular Weight:

123.86

EC Number:

232-017-6

MDL number:

MFCD00042545

UNSPSC Code:

12161600

PubChem Substance ID:

24860116

NACRES:

NA.22

form

powder and chunks

reaction suitability

core: titanium
reagent type: catalyst

density

2.798 g/mL at 25 °C (lit.)

SMILES string

F[Ti](F)(F)F

InChI

1S/4FH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XROWMBWRMNHXMF-UHFFFAOYSA-J

Application

Catalyst for:

Chemoselective synthesis and deprotection of geminal diacetates of aldehydes

Used for preparation of glycosyl fluorides; glycosylation; preparation of fluorohydrins; addition of carbanions to aldehydes and imines.

Pictograms

GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312 + H332,H314

Precautionary Statements

P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Biological response of human bone marrow mesenchymal stem cells to fluoride-modified titanium surfaces.

Luigi Guida et al.

Clinical oral implants research, 21(11), 1234-1241 (2010-05-26)

The aim of the present study was to examine the behaviour of human bone marrow-derived mesenchymal stem cells (BM-MSC) to fluoride-modified grit-blasted (F-TiO) titanium surfaces compared with grit-blasted ones (TiO). Implant surfaces were analysed by atomic force microscopy (AFM) and

The effect of daily fluoride mouth rinsing on enamel erosive/abrasive wear in situ.

K R Stenhagen et al.

Caries research, 47(1), 2-8 (2012-09-26)

It is not known whether application of fluoride agents on enamel results in lasting resistance to erosive/abrasive wear. We investigated if one daily mouth rinse with sodium fluoride (NaF), stannous fluoride (SnF(2)) or titanium tetrafluoride (TiF(4)) solutions protected enamel against

The erosion and abrasion-inhibiting effect of TiF(4) and NaF varnishes and solutions on enamel in vitro.

Flávia Mauad Levy et al.

International journal of paediatric dentistry, 22(1), 11-16 (2011-06-22)

OBJECTIVE. Previous in vitro study has shown that TiF(4) varnish might reduce enamel erosion. No data regarding the effect of this experimental varnish on enamel erosion plus abrasion, however, are available so far. Thus, this in vitro study aimed to

Effect of acidic fluoride treatments on early enamel erosion lesions--a comparison of calcium and profilometric analyses.

Carl Hjortsjö et al.

Archives of oral biology, 55(3), 229-234 (2010-02-02)

The protective effect of fluoride solutions against acidic challenge on enamel was tested in vitro using calcium- and profilometer analyses. HF-, SnF(2)-, TiF(4)- and NaF solutions (0.1M F(-), with a pH of 2.0, 2.9, 1.5, 7.3, respectively) and H(2)O were

Nanoleakage inhibition within hybrid layer using new protective chemicals and their effect on adhesion.

M Dündar et al.

Journal of dental research, 90(1), 93-98 (2010-10-14)

Hybrid-layer degradation occurs because of acidic properties of currently used adhesive systems. Titanium tetrafluoride couples with tooth surface, and titanium compounds are not substituted. Caffeic acid phenethyl esther inhibits endogenous matrix metalloproteinases that cause hybrid-layer degradation. It was hypothesized that

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