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Merck

442232-U

Supelco

1,2-二苯肼

analytical standard, ampule of 100 mg

别名:

氢化偶氮苯, 1,2-二苯肼, NSC 3510

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About This Item

线性分子式:
C6H5NHNHC6H5
CAS号:
分子量:
184.24
Beilstein:
639793
EC號碼:
MDL號碼:
分類程式碼代碼:
77101502
PubChem物質ID:
NACRES:
NA.24

等級

analytical standard

CofA

current certificate can be downloaded

包裝

ampule of 100 mg

技術

HPLC: suitable
gas chromatography (GC): suitable

mp

123-126 °C (lit.)

應用

cleaning products
cosmetics
environmental
food and beverages
personal care

格式

neat

儲存溫度

2-30°C

SMILES 字串

N(Nc1ccccc1)c2ccccc2

InChI

1S/C12H12N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10,13-14H

InChI 密鑰

YBQZXXMEJHZYMB-UHFFFAOYSA-N

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一般說明

1,2-Diphenylhydrazine is mainly used in the manufacture of fabrics and medicines. Its other applications include, but not limited to: a precursor of benzidine, an antisludging additive for motor oil, a constituent in photochromic resins as well as in polymers, and syntheses of hydrogen peroxide (H2O2) and several dyestuffs.

應用

作为以下反应的反应物:
  • 与有机金属钽配合物发生的插入反应
  • 三氯化钛(III)催化的还原反应,生成胺
  • 研究苯重排的机理
  • N-杂环稳定的甲硅烷基发生的反应
  • 二锰酰胺酰肼簇合物的合成
  • 铁介导的肼还原反应,生成亚芳基铁立方烷
1,2-Diphenylhydrazine may be used as an analytical standard for the determination of the analyte in landfill leachate, pharmaceutical process stream, and aqueous solutions by high-performance liquid chromatography (HPLC) and gas chromatography (GC) based analytical techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges


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分析证书(COA)

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Joonas Jernberg et al.
Talanta, 103, 384-391 (2012-12-04)
Nontarget analysis means that a sample is analysed without preselection of the studied analytes. While target analysis attempts to determine whether certain selected compounds are present in the sample, nontarget analysis is performed to explore what unknown compounds can be
Darol E Dodd et al.
International journal of toxicology, 31(6), 564-571 (2012-11-09)
Male F344 rats were exposed to hydrazobenzene (HZB) by dietary feed at concentrations of 0, 5, 20, 80, 200, or 300 ppm for 5 days, 2 weeks, 4 weeks, or 13 weeks duration. End points evaluated included clinical observations, body
Hydrazobenzene.
Report on carcinogens : carcinogen profiles, 10, 139-140 (2004-08-26)
H Fabre et al.
Journal of pharmaceutical sciences, 73(12), 1706-1709 (1984-12-01)
A high-performance liquid chromatographic method was developed for the simultaneous determination of azobenzene, hydrazobenzene, and four other decomposition products in phenylbutazone injectable formulations. Separation was achieved on a C18 column, with 0.1 M Tris-citrate buffer (pH 5.25) and acetonitrile (52:48)
Jenny V Lockard et al.
The journal of physical chemistry. A, 109(6), 1205-1215 (2006-07-13)
A quantitative model of mixed-valence excited-state spectroscopy is developed and applied to 2,3-diphenyl-2,3-diazabicyclo[2.2.2]octane. The lowest-energy excited state of this molecule arises from a transition from the ground state, where the charge is located on the hydrazine bridge, to an excited

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