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Merck

85440

Sigma-Aldrich

黑芥子硫苷酸钾水合物 水合物

≥99.0% (TLC)

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About This Item

经验公式(希尔记法):
C10H16KNO9S2 · xH2O
CAS号:
分子量:
397.46 (anhydrous basis)
MDL號碼:
分類程式碼代碼:
12352201
PubChem物質ID:
NACRES:
NA.25

生物源

plant (Brassica nigra)

品質等級

化驗

≥99.0% (TLC)

形狀

powder or crystals

光學活性

[α]20/D −17±1°, c = 1% in H2O

技術

thin layer chromatography (TLC): suitable

顏色

white to faint beige

mp

128 (dec.) (lit.)

正離子痕跡

K: 8.4-10.8

儲存溫度

room temp

SMILES 字串

[K+].[H]O[H].OC[C@H]1O[C@@H](S\C(CC=C)=N\OS([O-])(=O)=O)[C@H](O)[C@@H](O)[C@@H]1O

InChI

1S/C10H17NO9S2.K.H2O/c1-2-3-6(11-20-22(16,17)18)21-10-9(15)8(14)7(13)5(4-12)19-10;;/h2,5,7-10,12-15H,1,3-4H2,(H,16,17,18);;1H2/q;+1;/p-1/b11-6+;;/t5-,7-,8+,9-,10+;;/m1../s1

InChI 密鑰

IUBVMJHASFBYGW-WBMBWNLZSA-M

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應用

黑介子硫苷酸钾是一种硫代葡萄糖苷,被用作systrate以鉴定、区分和表征黑芥子酶/硫代葡糖苷葡糖水解酶/硫代葡糖苷酶。黑介子硫苷酸钾被用作分离和鉴定硫代葡萄糖苷过程的标准物质。

生化/生理作用

黑芥菜籽和辣根中含有β-D-硫代吡喃葡萄糖苷。硫代葡糖苷酶的底物。

其他說明

为了全面了解我们针对客户研究提供的各种单糖产品,建议您访问我们的碳水化合物分类页面。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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A.J. MacLeod et al.
Phytochemistry, 25, 1047-1047 (1986)
Vanessa Rungapamestry et al.
The British journal of nutrition, 99(4), 773-781 (2007-10-31)
Isothiocyanates have been implicated in the cancer-protective effects of brassica vegetables. When cabbage is consumed, sinigrin is hydrolysed by plant or microbial myrosinase partly to allyl isothiocyanate (AITC), which is mainly excreted as N-acetylcysteine conjugates (NAC) of AITC in urine.
Kari Jørgensen et al.
The Journal of experimental biology, 210(Pt 14), 2563-2573 (2007-07-03)
In nature, moths encounter nutritious and toxic substances in plants, and thus have to discriminate between a diversity of tastants. Whereas olfactory learning allowing memory of nutritious plants is well demonstrated, little is known about learning and memory of toxic
Richard A Lankau et al.
The American naturalist, 171(2), 150-161 (2008-01-17)
Plants interact with many different species throughout their life cycle. Recent work has shown that the ecological effects of multispecies interactions are often not predictable from studies of the component pairwise interactions. Little is known about how multispecies interactions affect
Kody A Belliveau et al.
Natural product research, 24(1), 24-33 (2009-12-17)
A simple procedure for extracting and purifying sinigrin from Oriental mustard (Brassica juncea) meal using cold water was developed. Subsequently, the chemical degradation of sinigrin due to enzymatic activity was monitored using (1)H NMR spectroscopy over the course of 30

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