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Merck

F0507

Sigma-Aldrich

甲酸

reagent grade, ≥95%

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About This Item

线性分子式:
HCOOH
CAS号:
分子量:
46.03
Beilstein:
1209246
EC號碼:
MDL號碼:
分類程式碼代碼:
12352106
PubChem物質ID:
NACRES:
NA.21

等級

reagent grade

品質等級

蒸汽密度

1.6 (vs air)

蒸汽壓力

44.8 mmHg ( 20 °C)

化驗

≥95%

形狀

liquid

自燃溫度

1004 °F

包含

<2.5% water as stabilizer

expl. lim.

57 %

雜質

≤1% acetic acid

折射率

n20/D 1.370 (lit.)

pH值

2.2 (20 °C, 2.2 g/L)

bp

100-101 °C (lit.)

mp

8.2-8.4 °C (lit.)

密度

1.22 g/mL at 25 °C (lit.)

儲存溫度

room temp

SMILES 字串

OC=O

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

InChI 密鑰

BDAGIHXWWSANSR-UHFFFAOYSA-N

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相关类别

一般說明

甲酸(HCOOH,FA)是最简单的羧酸,主要存在于昆虫的叮咬和蛰伤中。由于其毒性低、可回收、易于使用以及在环境条件下呈液态,它被广泛用作储氢分子。

應用

甲酸用作还原剂:

  • 用于从氧化石墨烯合成石墨烯。
  • 通过胶体钯催化还原铬(Cr(VI) 到 Cr(III))。
在由 2-(2-氯苯基)-2-硝基环己酮(2-CPNCH)还原成氯胺酮的合成过程中,它还可用作Eschweiler-Clarke反应的试剂。

此外,在葡萄糖的呋喃糖形式转化为吡喃糖形式的过程中,以及在催化转移加氢反应中,它还可用作氢供体。

  • Electrochemical CO(2) Reduction on Metallic and Oxidized Tin: This study uses grand-canonical density functional theory (DFT) and in situ attenuated total reflectance surface-enhanced infrared absorption spectroscopy (ATR-SEIRA) to investigate electrochemical carbon dioxide reduction on tin surfaces, where formic acid could play a role in understanding reaction mechanisms (Whittaker et al., 2024).

  • Simultaneous Measurement of COVID-19 Treatment Drugs: This research demonstrates the use of UPLC-MS/MS for the simultaneous measurement of COVID-19 treatment drugs in rat plasma, indicating the importance of formic acid in preparing samples or as a mobile phase additive for better chromatographic separation (Zhou et al., 2024).

  • Metabolite Profiling of Liquiritin: The study involves metabolite profiling using ultra-high-performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS), where formic acid is likely utilized in sample preparation or chromatographic processes (Chen et al., 2024).

  • Analysis of Cocaine and Its Metabolites: This article explores solid-phase extraction followed by UHPLC-ESI-MS/MS analysis of cocaine metabolites, a method that often incorporates formic acid to enhance the ionization of analytes (Makhdoom et al., 2024).

  • Determination of Antimicrobial Compounds in Pigs: This research uses UHPLC-MS/MS for the simultaneous determination of various antimicrobial compounds, demonstrating formic acid′s role in sample processing and chromatographic separation (Nowacka-Kozak et al., 2024).

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

121.1 °F - closed cup

閃點(°C)

49.5 °C - closed cup


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