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Merck

307483

Sigma-Aldrich

氯化铜(II) 二水合物

ACS reagent, ≥99.0%

别名:

氯化铜 二水合物

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About This Item

线性分子式:
CuCl2 · 2H2O
CAS号:
分子量:
170.48
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NB.24

等級

ACS reagent

蒸汽密度

>1 (vs air)

化驗

≥99.0%

形狀

crystalline powder
crystals or granules

反應適用性

reagent type: catalyst
core: copper

雜質

≤0.01% insolubles

mp

100 °C (dec.) (lit.)

負離子痕跡

nitrate (NO3-): ≤0.015%
sulfate (SO42-): ≤0.005%

正離子痕跡

Ca: ≤0.005%
Fe: ≤0.005%
K: ≤0.01%
Na: ≤0.02%
Ni: ≤0.01%

SMILES 字串

Cl[Cu]Cl.[H]O[H].[H]O[H]

InChI

1S/2ClH.Cu.2H2O/h2*1H;;2*1H2/q;;+2;;/p-2

InChI 密鑰

MPTQRFCYZCXJFQ-UHFFFAOYSA-L

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相关类别

應用

六水合氯化铜(II)可作为催化剂用于:
  • 通过与苯肼、水合肼和取代的芳基异硫氰酸酯反应,将二美酮转化为 N-芳基肼碳硫酰胺基茚唑衍生物。
  • 在联吡啶配体存在下,芳基硼酸、芳基氰胺和胺的三组分多米诺反应合成 2-氨基苯并咪唑。

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Interaction of hydrazine with copper (II) chloride in acidic solutions. Formation, spectral and magnetic properties, and structures of copper (II), copper (I), and mixed-valence species.
Brown DB, et al.
Inorganic Chemistry, 18(10), 2635-2641 (1979)
An X-ray refinement of the crystal structure of copper (II) chloride dihydrate.
Engberg ?.
Acta Chemica Scandinavica, 24(10), 6-6 (1970)
Deprotection of t-butyldimethylsiloxy (TBDMS) protecting group with catalytic copper (II) chloride dihydrate.
TAN ZP, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 11(9), 753-756 (2000)
Regeneration of carbonyl compounds from semicarbazones by copper (II) chloride dihydrate.
Ram RN and Varsha K.
Tetrahedron Letters, 32(41), 5829-5832 (1991)
María S Islas et al.
Inorganic chemistry, 53(11), 5724-5737 (2014-05-16)
A new Cu(II) complex with the antihypertensive drug telmisartan, [Cu8Tlm16]·24H2O (CuTlm), was synthesized and characterized by elemental analysis and electronic, FTIR, Raman and electron paramagnetic resonance spectroscopy. The crystal structure (at 120 K) was solved by X-ray diffraction methods. The

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