所有图片(5)
About This Item
经验公式(希尔记法):
Ag2O
CAS号:
分子量:
231.74
EC號碼:
MDL號碼:
分類程式碼代碼:
12352303
PubChem物質ID:
NACRES:
NA.21
化驗:
99%
形狀:
powder or chunks
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應用
在对称二醇与烷基卤化物的单保护作用下,以良好至极好的产率进行介导。
氧化银(I)可用于调解以下过程:
- 卤代烃存在下对称碳化物的选择性单烷基化。
- 钯催化芳基和烯基硅醇与有机卤化物的交叉偶联。
- 钯催化的芳基和烯基卤化物分别与末端炔烃反应形成芳基化炔烃或烯基化炔烃。
法律資訊
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Danger
危險聲明
危險分類
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1
儲存類別代碼
5.1A - Strongly oxidizing hazardous materials
水污染物質分類(WGK)
WGK 2
閃點(°F)
Not applicable
閃點(°C)
Not applicable
其他客户在看
A New Transformation of Silanols. Palladium-Catalyzed Cross-Coupling with Organic Halides in the Presence of Silver (I) Oxide
Hirabayashi K, et al.
Organic Letters, 1(2), 299-302 (1999)
Highly selective silver (I) oxide mediated monoprotection of symmetrical diols
Bouzide A and Sauve G.
Tetrahedron Letters, 38(34), 5945-5948 (1997)
Abderrahim Bouzide et al.
Organic letters, 4(14), 2329-2332 (2002-07-06)
[reaction: see text] The reaction of symmetrical diols and oligo(ethylene glycol)s with a stoichiometric amount of p-toluenesulfonyl chloride in the presence of silver(I) oxide and a catalytic amount of potassium iodide led selectively to the monotosylate derivatives in high yields.
Eagleson M.
Concise Encyclopedia Chemistry, 124-124 (1994)
Bouzide, A. Sauve, G.
Tetrahedron Letters, 38, 5945-5945 (1997)
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