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Merck

161527

Sigma-Aldrich

硫氢化钠 水合物

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About This Item

线性分子式:
NaSH·xH2O
分子量:
56.06 (anhydrous basis)
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.55

形狀

chips
flakes

品質等級

濃度

≥60% (by Na2S2O3, titration)

mp

52-54 °C (lit.)

SMILES 字串

[Na]S.[H]O[H]

InChI

1S/Na.H2O.H2S/h;2*1H2/q+1;;/p-1

InChI 密鑰

ZNKXTIAQRUWLRL-UHFFFAOYSA-M

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一般說明

氢硫化钠水合物是钠的水合无机盐。它参与合成(E)-2-氰基-2-(噻唑烷-2-亚基)硫代乙酰胺。

應用

它可以用作硫亲核试剂以诱导α,β-二氯乙烯基酮中的CS键形成,以形成5-至8-元环状硫醚。
氢硫化钠水合物可用于以下合成:
  • 苯并噻唑
  • 4-甲氧基苯并硫代酰胺
  • 2-(4-甲氧基苯基)咪唑啉
  • 7-氯-4′-甲氧基硫黄酮

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral - Aquatic Acute 1 - Skin Corr. 1B

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

194.0 °F - closed cup

閃點(°C)

90 °C - closed cup


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Min Sun et al.
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Two series of novel diaryl ureas have been designed and synthesized, with their in vitro antitumor effect screened on human non-small cell lung cancer (NSCLC) cell line A549 and human breast cancer cell line MDA-MB-231. Some target compounds demonstrated significant
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Life sciences, 232, 116650-116650 (2019-07-16)
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Biology open, 8(7) (2019-07-19)
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Practical and Versatile Synthesis of Thioflavones from 2-Bromobenzoyl Chlorides.
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J. Korean Chem. Soc., 59(3) (2015)
Synthesis of Benzothiazoles through Copper-Catalyzed One-Pot Three-Component Reactions with Use of Sodium Hydrosulfide as a Sulfur Surrogate.
Park N, et al.
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