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等級
purum
形狀
liquid
反應適用性
reagent type: catalyst
core: iron
環保替代產品特色
Catalysis
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sustainability
Greener Alternative Product
濃度
45% (FeCl3)
環保替代類別
, Aligned
SMILES 字串
Cl[Fe](Cl)Cl
InChI
1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI 密鑰
RBTARNINKXHZNM-UHFFFAOYSA-K
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一般說明
我们致力于为您提供更环保的替代产品,以符合“绿色化学的 12 项原则”的一项或多项原则要求。这种铁催化剂价格便宜且对环境友好。 点击此处了解更多信息。
氯化铁(III)是一种温和的氧化剂。它被广泛用作有机合成中的 Lewis酸。在水中结晶时,它形成水合物。它可以通过在约650℃下使氯气流过废铁进行制备。
應用
氯化铁(III)可用于吡咯的聚合和菲环的制备。它被广泛用于以下反应:
- 聚合反应
- 氧化反应
- 氧化偶联
- 还原反应
- C−C键形成
- Ferrier重排
- 一锅法多组分缩合
- Friedel-Crafts反应
- 环化反应
- 苷化反应
- Prins成环反应
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1
儲存類別代碼
8B - Non-combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 1
閃點(°F)
Not applicable
閃點(°C)
Not applicable
其他客户在看
Optimum reaction conditions for the polymerization of pyrrole by iron (III) chloride in aqueous solution.
Synthetic Metals, 20(3), 365-371 (1987)
Recent uses of iron (III) chloride in organic synthesis.
Current Organic Chemistry, 10(4), 457-476 (2006)
The Journal of organic chemistry, 74(2), 935-938 (2008-12-05)
Easily available and nontoxic FeCl(3) catalyzes intramolecular oxidative coupling for the direct construction of the phenanthrene ring using meta-chloroperbenzoic acid as sole oxidant at room temperature in excellent yields. The mechanistic investigations show that FeCl(3)-catalyzed coupling proceeds through the heterolytic
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
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